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New synthetic approach to a [1.1.6] metapara cyclophane derivative via Suzuki-Miyaura cross-coupling and ring-closing metathesis

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Title New synthetic approach to a [1.1.6] metapara cyclophane derivative via Suzuki-Miyaura cross-coupling and ring-closing metathesis
 
Creator KOTHA, S
MANDAL, K
ARORA, KK
PEDIREDDI, R
 
Subject organic-synthesis
dimerization
cyclophanes
olefin metathesis
palladium
ruthenium
suzuki-miyaura cross-coupling
 
Description The synthesis of a [1.1.6] metapara cyclophane derivative, 1,5(1,4),3(1,3)-tribenzenacycloun-decaphan-8-ene-6,11-dione, has been achieved via the Suzuki-Miyaura cross-coupling of alpha,alpha'-dibromo-m-xylene with an arylboronic acid derivative followed by an allylation and ring-closing metathesis reaction sequence.
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2011-09-01T18:42:51Z
2011-12-26T12:59:45Z
2011-12-27T05:52:34Z
2011-09-01T18:42:51Z
2011-12-26T12:59:45Z
2011-12-27T05:52:34Z
2005
 
Type Article
 
Identifier ADVANCED SYNTHESIS & CATALYSIS, 347(9), 1215-1218
1615-4150
http://dx.doi.org/10.1002/adsc.200404373
http://dspace.library.iitb.ac.in/xmlui/handle/10054/12843
http://hdl.handle.net/10054/12843
 
Language en