Suzuki-Miyaura cross-coupling and ring-closing metathesis: A strategic combination for the synthesis of cyclophane derivatives
DSpace at IIT Bombay
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Title |
Suzuki-Miyaura cross-coupling and ring-closing metathesis: A strategic combination for the synthesis of cyclophane derivatives
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Creator |
KOTHA, S
MANDAL, K |
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Subject |
allylic acetate isomerization
imido alkylidene complexes diels-alder reaction olefin-metathesis organic-synthesis ruthenium benzylidenes claisen rearrangement arylboronic acids grubbs catalyst aryl cyclophanes isomerization olefin metathesis palladium ruthenium suzuki-miyaura cross-coupling |
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Description |
The synthesis of cyclophane derivatives through a sequence involving Suzuki-Miyaura cross-coupling between alpha,alpha'-dibromo-m-xylene and arylboronic acid derivatives, alkenylation and ring-closing metathesis has been achieved. One of the cyclophanes was obtained by tandem isomerization and metathesis. Significant magnetic anisotropic effects on the intra-annular hydrogen atoms were observed.
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Publisher |
WILEY-V C H VERLAG GMBH
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Date |
2011-09-01T20:56:19Z
2011-12-26T12:59:47Z 2011-12-27T05:52:40Z 2011-09-01T20:56:19Z 2011-12-26T12:59:47Z 2011-12-27T05:52:40Z 2006 |
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Type |
Article
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Identifier |
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (23), 5387-5393
1434-193X http://dx.doi.org/10.1002/ejoc.200600549 http://dspace.library.iitb.ac.in/xmlui/handle/10054/12865 http://hdl.handle.net/10054/12865 |
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Language |
en
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