Synthesis of C-3-symmetric nano-sized Polyaromatic compounds by trimerization and Suzuki-Miyaura cross-coupling reactions
DSpace at IIT Bombay
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Title |
Synthesis of C-3-symmetric nano-sized Polyaromatic compounds by trimerization and Suzuki-Miyaura cross-coupling reactions
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Creator |
KOTHA, S
KASHINATH, D LAHIRI, K SUNOJ, RB |
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Subject |
organic electroluminescent devices
amino-acid derivatives 9,10-diarylanthracene derivatives phenylalanine peptides dendrimers molecules series 1,3,5-trinitrobenzene absorption complexes c-c coupling cyclotrimerizations nanostructures polycycles semi-empirical calculations |
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Description |
Various C-3-symmetric molecules were prepared by trimerization of acetyl aromatic compounds and subsequently coupled with various boronic acids under Pd-0 catalysis conditions to generate oligoaryl/-heteroaryl C-3-symmetric molecules. Several furan- and thiophene-containing star-shaped molecules were prepared by the use of Suzuki-Miyaura cross-coupling as a key step. Structural and conformational details were explored by semi-empirical molecular orbital theory using the AM1 method.
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Publisher |
WILEY-V C H VERLAG GMBH
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Date |
2011-09-01T21:39:51Z
2011-12-26T12:59:48Z 2011-12-27T05:52:42Z 2011-09-01T21:39:51Z 2011-12-26T12:59:48Z 2011-12-27T05:52:42Z 2004 |
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Type |
Article
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Identifier |
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (19), 4003-4013
1434-193X http://dx.doi.org/10.1002/ejoc.200400257 http://dspace.library.iitb.ac.in/xmlui/handle/10054/12875 http://hdl.handle.net/10054/12875 |
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Language |
en
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