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Synthesis of symmetrical sulfones from rongalite: Expansion to cyclic sulfones by ring-closing metathesis

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Title Synthesis of symmetrical sulfones from rongalite: Expansion to cyclic sulfones by ring-closing metathesis
 
Creator KOTHA, S
KHEDKAR, P
GHOSH, AK
 
Subject sodium formaldehyde sulfoxylate
solid-phase synthesis
olefin-metathesis
cleavage strategy
dibenzyl sulfones
one-step
sulfonamides
heterocycles
catalysts
rucl2(=chr)(pr(3))(2)
rongalite
ring-closing metathesis
sulfones
sulfur heterocycles
 
Description A simple method for the synthesis of symmetrical sulfones using rongalite has been developed. Terminally olefinic sulfone derivatives were subjected to ring-closing metathesis (RCM) reactions to generate cyclic sulfones. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2011-09-01T21:49:42Z
2011-12-26T12:59:48Z
2011-12-27T05:52:43Z
2011-09-01T21:49:42Z
2011-12-26T12:59:48Z
2011-12-27T05:52:43Z
2005
 
Type Article
 
Identifier EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, (16), 3581-3585
1434-193X
http://dx.doi.org/10.1002/ejoc.200500264
http://dspace.library.iitb.ac.in/xmlui/handle/10054/12877
http://hdl.handle.net/10054/12877
 
Language en