Synthesis and structural characterisation of a new mu(2)-Te bridged complex of molybdenum with oxo and imido ligands
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Title |
Synthesis and structural characterisation of a new mu(2)-Te bridged complex of molybdenum with oxo and imido ligands
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Creator |
MATHUR, P
GHOSE, S HOSSAIN, MM VAHRENKAMP, H |
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Subject |
crystal-structure
cluster compounds reactivity catalysts sulfido ammoxidation chemistry oxidation molybdate selenium molybdenum tellurium ore imido azide dinuclear |
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Description |
Reflux of a benzene solution of Cp2Mo2Fe2(CO)(7)Te-2 and PhN3 in the presence of air afforded the new compound CP2Mo2O2(mu-Te)(mu-NC6H5) in 33% yield. It was characterised by IR and H-1 and Te-125 NMR. spectroscopy. Crystallographic analysis established its structure. The structure can be described as consisting of a CpMo-MoCp unit, bridged by a mu-Te atom and an imido ligand. Also bonded lo each Mo atom is a terminally bonded oxo group.
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Publisher |
ELSEVIER SCIENCE SA LAUSANNE
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Date |
2011-07-29T15:47:25Z
2011-12-26T12:48:46Z 2011-12-27T05:52:51Z 2011-07-29T15:47:25Z 2011-12-26T12:48:46Z 2011-12-27T05:52:51Z 1997 |
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Type |
Article
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Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 538(1-2), 185-188
0022-328X http://dx.doi.org/10.1016/S0022-328X(96)06903-3 http://dspace.library.iitb.ac.in/xmlui/handle/10054/7754 http://hdl.handle.net/10054/7754 |
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Language |
en
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