Record Details

Synthesis and structural characterisation of a new mu(2)-Te bridged complex of molybdenum with oxo and imido ligands

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Synthesis and structural characterisation of a new mu(2)-Te bridged complex of molybdenum with oxo and imido ligands
 
Creator MATHUR, P
GHOSE, S
HOSSAIN, MM
VAHRENKAMP, H
 
Subject crystal-structure
cluster compounds
reactivity
catalysts
sulfido
ammoxidation
chemistry
oxidation
molybdate
selenium
molybdenum
tellurium
ore
imido
azide
dinuclear
 
Description Reflux of a benzene solution of Cp2Mo2Fe2(CO)(7)Te-2 and PhN3 in the presence of air afforded the new compound CP2Mo2O2(mu-Te)(mu-NC6H5) in 33% yield. It was characterised by IR and H-1 and Te-125 NMR. spectroscopy. Crystallographic analysis established its structure. The structure can be described as consisting of a CpMo-MoCp unit, bridged by a mu-Te atom and an imido ligand. Also bonded lo each Mo atom is a terminally bonded oxo group.
 
Publisher ELSEVIER SCIENCE SA LAUSANNE
 
Date 2011-07-29T15:47:25Z
2011-12-26T12:48:46Z
2011-12-27T05:52:51Z
2011-07-29T15:47:25Z
2011-12-26T12:48:46Z
2011-12-27T05:52:51Z
1997
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 538(1-2), 185-188
0022-328X
http://dx.doi.org/10.1016/S0022-328X(96)06903-3
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7754
http://hdl.handle.net/10054/7754
 
Language en