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Synthesis and structural characterisation of a novel tris-methylene bridged compound (NO)(4)Fe2Se(mu-CH2)(3)

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Title Synthesis and structural characterisation of a novel tris-methylene bridged compound (NO)(4)Fe2Se(mu-CH2)(3)
 
Creator MATHUR, P
MANIMARAN, B
HOSSAIN, MM
RHEINGOLD, AL
LIABLESANDS, LM
YAP, GPA
 
Subject bidentate organosulfur ligands
chalcogen carbonyl-compounds
acetylenic bond reduction
crystal-structure
metal-surfaces
te bond
complexes
chemistry
fe2(co)6(mu-se2)
polymerization
chalcogen
alkylidene clusters
 
Description The tris-methylene bridged compound (NO)(4)Fe2Se(mu-CH2)(3) has been isolated. It has been characterised by IR and H-1, C-13, and Se-77 NMR spectroscopy. Its structure has been determined by single-crystal X-ray diffraction methods. The structure consists of a heavy atom triangle consisting of one Se and two Fe atoms. The Fe-Fe and the two Fe-Se edges are bridged by methylene groups. (C) 1997 Elsevier Science S.A.
 
Publisher ELSEVIER SCIENCE SA LAUSANNE
 
Date 2011-07-29T15:55:50Z
2011-12-26T12:48:46Z
2011-12-27T05:52:54Z
2011-07-29T15:55:50Z
2011-12-26T12:48:46Z
2011-12-27T05:52:54Z
1997
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 540(1-2), 165-168
0022-328X
http://dx.doi.org/10.1016/S0022-328X(97)00134-4
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7755
http://hdl.handle.net/10054/7755
 
Language en