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SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NEW METHYLENE BRIDGED DOUBLE BUTTERFLY SHAPED COMPLEX [(MU-CH3TE)FE2(CO)6]2[MU-TE(CH2)TE-MU]
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NEW METHYLENE BRIDGED DOUBLE BUTTERFLY SHAPED COMPLEX [(MU-CH3TE)FE2(CO)6]2[MU-TE(CH2)TE-MU]
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| Creator |
MATHUR, P
REDDY, VD DAS, K SINHA, UC |
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| Subject |
metal
bond te |
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| Description |
The new methylene bridged compound [(mu-CH3Te)Fe2(CO)6]2[mu-Te(CH2)Te-mu] has been prepared from the reaction at room temperature of Fe3(CO)9(mu-3-Te)2 and excess diazomethane. The compound was subjected to X-ray structural analysis. The crystals were monoclinic, space group C2/c, a = 28.865(10), b = 13.787(7), c = 14.733(4) A, beta = 104.67(2)-degrees, U = 5672 A3, Z = 8, D(c) = 2.637 g cm-3. The structure consists of two '(CO)6Fe2Te(CH3)Te' units connected by a CH2 group.
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| Publisher |
ELSEVIER SCIENCE SA LAUSANNE
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| Date |
2011-07-29T16:08:29Z
2011-12-26T12:48:47Z 2011-12-27T05:52:57Z 2011-07-29T16:08:29Z 2011-12-26T12:48:47Z 2011-12-27T05:52:57Z 1991 |
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| Type |
Article
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| Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 409(1-2), 255-261
0022-328X http://dx.doi.org/10.1016/0022-328X(91)86151-F http://dspace.library.iitb.ac.in/xmlui/handle/10054/7757 http://hdl.handle.net/10054/7757 |
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| Language |
en
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