Differential Reactivity Pattern of Hybrid o-Quinodimethane Precursors: Strategic Expansion to Annulated Benzocycloalkanes via Rongalite
DSpace at IIT Bombay
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Title |
Differential Reactivity Pattern of Hybrid o-Quinodimethane Precursors: Strategic Expansion to Annulated Benzocycloalkanes via Rongalite
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Creator |
KOTHA, S
KHEDKAR, P |
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Subject |
amino-acid derivatives
diels-alder reactions intramolecular cycloaddition reactions sodium formaldehyde sulfoxylate natural-product hybrids cross-coupling reaction organic-synthesis symmetric sulfones synthetic approach ortho-xylylenes |
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Description |
A hybrid benzocyclobutene (BCB) molecular frames embedding sultine or sulfone moiety has been synthesized via utilization of rongalite. The selective Diels-Alder reaction has been realized at sultine or sulfone terminus in the hybrid BCB system to prepare functionalized BCB molecular frames. The methodology has been generalized for assembling various benzocycloalkanes containing a sultine unit and the strategy has been expanded to generate various annulated benzocycloalkanes.
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Publisher |
AMER CHEMICAL SOC
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Date |
2011-07-13T23:08:34Z
2011-12-26T12:47:26Z 2011-12-27T05:53:02Z 2011-07-13T23:08:34Z 2011-12-26T12:47:26Z 2011-12-27T05:53:02Z 2009 |
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Type |
Article
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Identifier |
JOURNAL OF ORGANIC CHEMISTRY, 74(15), 5667-5670
0022-3263 http://dx.doi.org/10.1021/jo900658z http://dspace.library.iitb.ac.in/xmlui/handle/10054/3797 http://hdl.handle.net/10054/3797 |
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Language |
en
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