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Novel entry into oxepane–diquinane and oxepane–sterpurane hybrids: synthesis and photochemistry of 3-oxatricyclo[7.2.2.01,7]tridecenones
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
Novel entry into oxepane–diquinane and oxepane–sterpurane hybrids: synthesis and photochemistry of 3-oxatricyclo[7.2.2.01,7]tridecenones
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| Creator |
SINGH, VISHWAKARMA
VEDANTHAM, PUNITHA KANE, VINAYAK V POLBORN, KURT |
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| Subject |
intramolecular cycloaddition
photoreaction |
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| Description |
A new synthesis of 3-oxatricyclo[7.2.2.01,7]tridecenones via intramolecular π4s+π2s cycloaddition in cyclohexa-2,4-dienones is described. Their photochemical reactions leading to oxepane–diquinane and oxepane–sterpurane hybrids are depicted. The crystal structure of a key intermediate is also presented.
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| Publisher |
Elsevier
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| Date |
2009-02-21T11:27:39Z
2011-11-25T17:18:58Z 2011-12-26T13:05:51Z 2011-12-27T05:53:45Z 2009-02-21T11:27:39Z 2011-11-25T17:18:58Z 2011-12-26T13:05:51Z 2011-12-27T05:53:45Z 2003 |
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| Type |
Article
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| Identifier |
Tetrahedron Letters 44(3), 475-478
0040-4039 http://dx.doi.org/10.1016/S0040-4039(02)02611-4 http://hdl.handle.net/10054/729 http://dspace.library.iitb.ac.in/xmlui/handle/10054/729 |
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| Language |
en
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