Synthesis, spectroscopic and structural characterisation of {(CO)(3)Fe(mu-CH2)Se}(2) and (CO)(6)Fe-2{mu-Se(CH2)(n)Se} (n=1,2)
DSpace at IIT Bombay
View Archive InfoField | Value | |
Title |
Synthesis, spectroscopic and structural characterisation of {(CO)(3)Fe(mu-CH2)Se}(2) and (CO)(6)Fe-2{mu-Se(CH2)(n)Se} (n=1,2)
|
|
Creator |
MATHUR, P
MANIMARAN, B TRIVEDI, R HOSSAIN, MM ARABATTI, M |
|
Subject |
bidentate organosulfur ligands
acetylenic bond reduction crystal-structure methylene groups metal-complexes cluster chemistry te se fe2(co)6(mu-se2) iron selenium methylene carbonyl x-ray diffraction crystal structure |
|
Description |
From the room temperature reaction of (CO)(9)Fe-3(mu(3)-Se)(2) or (CO)(6)Fe-2(mu-Se-2) with diazomethane, four products were isolated; {(CO)(3)Fe(mu-CH2)Se}(2) (1), (CO)(6)Fe-2(mu-SeCH3)(2) (2), (CO)(6)Fe-2(mu-SeCH2Se) (3) and (CO)(6)Fe-2(mu-SeCH2CH2Se) (4). All four 77 compounds were characterised by IR, H-1, C-13, and Se-77 NMR spectroscopy. Structures of 1, 3 and 4 were established by single crystal X-ray structure analyses.
|
|
Publisher |
ELSEVIER SCIENCE SA LAUSANNE
|
|
Date |
2011-07-29T16:39:23Z
2011-12-26T12:48:48Z 2011-12-27T05:53:58Z 2011-07-29T16:39:23Z 2011-12-26T12:48:48Z 2011-12-27T05:53:58Z 1996 |
|
Type |
Article
|
|
Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 515(1-2), 155-162
0022-328X http://dx.doi.org/10.1016/0022-328X(95)06056-3 http://dspace.library.iitb.ac.in/xmlui/handle/10054/7764 http://hdl.handle.net/10054/7764 |
|
Language |
en
|
|