Record Details

Synthesis and reactions of silicon containing cyclic α-amino acid derivatives

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Synthesis and reactions of silicon containing cyclic α-amino acid derivatives
 
Creator KOTHA, SAMBASIVARAO
BRAHMACHARY, ENUGURTHI
 
Subject synthesis
amino acids
chromatography
cycloaddition
 
Description A simple synthesis of a new amino acid derivative 5,6-bis(trimethylsilyl)indanylglycine via cobalt mediated [2 + 2 + 2] cycloaddition strategy is described. Co-trimerization of diyne building block containing amino acid moiety with bis(trimethylsilyl)acetylene in presence of CpCo(CO)2 catalyst afforded the silylated indane-based α-amino acid (AAA) derivative. Electrophilic aromatic substitution reaction, ipso to the trimethylsilyl group gave highly functionalised indane-based AAA derivatives.
 
Publisher Elsevier
 
Date 2009-02-24T12:19:21Z
2011-11-25T17:45:02Z
2011-12-26T13:06:17Z
2011-12-27T05:54:06Z
2009-02-24T12:19:21Z
2011-11-25T17:45:02Z
2011-12-26T13:06:17Z
2011-12-27T05:54:06Z
2004
 
Type Article
 
Identifier Journal of Organometallic Chemistry 689(1), 158-163
0022-328X
http://dx.doi.org/10.1016/j.jorganchem.2003.09.044
http://hdl.handle.net/10054/766
http://dspace.library.iitb.ac.in/xmlui/handle/10054/766
 
Language en