Synthesis and reactions of silicon containing cyclic α-amino acid derivatives
DSpace at IIT Bombay
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Title |
Synthesis and reactions of silicon containing cyclic α-amino acid derivatives
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Creator |
KOTHA, SAMBASIVARAO
BRAHMACHARY, ENUGURTHI |
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Subject |
synthesis
amino acids chromatography cycloaddition |
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Description |
A simple synthesis of a new amino acid derivative 5,6-bis(trimethylsilyl)indanylglycine via cobalt mediated [2 + 2 + 2] cycloaddition strategy is described. Co-trimerization of diyne building block containing amino acid moiety with bis(trimethylsilyl)acetylene in presence of CpCo(CO)2 catalyst afforded the silylated indane-based α-amino acid (AAA) derivative. Electrophilic aromatic substitution reaction, ipso to the trimethylsilyl group gave highly functionalised indane-based AAA derivatives.
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Publisher |
Elsevier
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Date |
2009-02-24T12:19:21Z
2011-11-25T17:45:02Z 2011-12-26T13:06:17Z 2011-12-27T05:54:06Z 2009-02-24T12:19:21Z 2011-11-25T17:45:02Z 2011-12-26T13:06:17Z 2011-12-27T05:54:06Z 2004 |
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Type |
Article
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Identifier |
Journal of Organometallic Chemistry 689(1), 158-163
0022-328X http://dx.doi.org/10.1016/j.jorganchem.2003.09.044 http://hdl.handle.net/10054/766 http://dspace.library.iitb.ac.in/xmlui/handle/10054/766 |
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Language |
en
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