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Synthesis of benzocycloheptene-based amino acid derivatives via a [4+2] cycloaddition reaction as a key step

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Field Value
 
Title Synthesis of benzocycloheptene-based amino acid derivatives via a [4+2] cycloaddition reaction as a key step
 
Creator KOTHA, SAMBASIVARAO
SREENIVASACHARY, NAMPALLY
BRAHMACHARY, ENUGURTHI
 
Subject amino acids
cycloaddition
dienes
derivatives
 
Description The seven-membered diene 5 is prepared from 2-butyne-1,4-diol using double orthoester Claisen rearrangement reaction as a key step. The Diels–Alder reaction of the diene 5 with various dienophiles followed by oxidation delivered the benzocycloheptene-based α-amino acid derivatives in very good yields.
 
Publisher Elsevier
 
Date 2009-02-25T09:28:44Z
2011-11-25T17:47:02Z
2011-12-26T13:06:18Z
2011-12-27T05:54:07Z
2009-02-25T09:28:44Z
2011-11-25T17:47:02Z
2011-12-26T13:06:18Z
2011-12-27T05:54:07Z
2001
 
Type Article
 
Identifier Tetrahedron 57(29), 6261-6265
0040-4020
http://dx.doi.org/10.1016/S0040-4020(01)00575-0
http://hdl.handle.net/10054/770
http://dspace.library.iitb.ac.in/xmlui/handle/10054/770
 
Language en