Record Details

Studies on alkylation of bicyclo[2.2.2]octenones and 3,3-sigmatropic shift: synthesis of advanced cis-decalins

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Studies on alkylation of bicyclo[2.2.2]octenones and 3,3-sigmatropic shift: synthesis of advanced cis-decalins
 
Creator SINGH, VISHWAKARMA
IYER, SRIDHAR R
 
Subject stereocentres
chromatography
alkylation
spectrophotometers
 
Description A stereoselective method for alkylation of bicyclo[2.2.2]octenones and their 3,3-sigmatropic shift leading to cis-decalins containing various types of appendages is described. A simple and convenient method for the introduction of a butenyl chain onto the bicyclooctenones employing 1,4-dibromobutane as an equivalent of 4-bromobutene, was developed.
 
Publisher Elsevier
 
Date 2009-02-20T07:28:36Z
2011-11-25T17:36:00Z
2011-12-26T13:06:21Z
2011-12-27T05:54:11Z
2009-02-20T07:28:36Z
2011-11-25T17:36:00Z
2011-12-26T13:06:21Z
2011-12-27T05:54:11Z
2005
 
Type Article
 
Identifier Tetrahedron 61(2), 457-462
0040-4020
http://dx.doi.org/10.1016/j.tet.2004.10.066
http://hdl.handle.net/10054/718
http://dspace.library.iitb.ac.in/xmlui/handle/10054/718
 
Language en