Studies on alkylation of bicyclo[2.2.2]octenones and 3,3-sigmatropic shift: synthesis of advanced cis-decalins
DSpace at IIT Bombay
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Title |
Studies on alkylation of bicyclo[2.2.2]octenones and 3,3-sigmatropic shift: synthesis of advanced cis-decalins
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Creator |
SINGH, VISHWAKARMA
IYER, SRIDHAR R |
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Subject |
stereocentres
chromatography alkylation spectrophotometers |
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Description |
A stereoselective method for alkylation of bicyclo[2.2.2]octenones and their 3,3-sigmatropic shift leading to cis-decalins containing various types of appendages is described. A simple and convenient method for the introduction of a butenyl chain onto the bicyclooctenones employing 1,4-dibromobutane as an equivalent of 4-bromobutene, was developed.
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Publisher |
Elsevier
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Date |
2009-02-20T07:28:36Z
2011-11-25T17:36:00Z 2011-12-26T13:06:21Z 2011-12-27T05:54:11Z 2009-02-20T07:28:36Z 2011-11-25T17:36:00Z 2011-12-26T13:06:21Z 2011-12-27T05:54:11Z 2005 |
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Type |
Article
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Identifier |
Tetrahedron 61(2), 457-462
0040-4020 http://dx.doi.org/10.1016/j.tet.2004.10.066 http://hdl.handle.net/10054/718 http://dspace.library.iitb.ac.in/xmlui/handle/10054/718 |
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Language |
en
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