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Hydroxyalkylation of conjugated nitroalkenes with activated nonenolizable carbonyl compounds

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Field Value
 
Title Hydroxyalkylation of conjugated nitroalkenes with activated nonenolizable carbonyl compounds
 
Creator DEB, INDUBHUSAN
DADWAL, MAMTA
SHAIKH, MOBIN M
NAMBOOTHIRI, IRISHI NN
 
Subject morita-baylis hilman reaction
acetonitrile
activated carbon
conjugated
 
Description The Morita-Baylis-Hillman reaction of a variety of conjugated nitroalkenes with activated nonenolizable carbonyl compounds such as glyoxylate, trifluoropyruvate, pyruvaldehyde, and ninhydrin in the presence of 40-100 mol % of DMAP in acetonitrile or 100 mol % of imidazole in CHCl3 or THF provided the adducts in decent to good yields. In most cases, the reactions catalyzed by DMAP in acetonitrile were faster and provided the desired MBH adducts in higher yields as compared to the imidazole catalyzed reactions.
 
Publisher American Chemical Society
 
Date 2009-02-25T12:23:10Z
2011-11-25T17:53:03Z
2011-12-26T13:06:22Z
2011-12-27T05:54:11Z
2009-02-25T12:23:10Z
2011-11-25T17:53:03Z
2011-12-26T13:06:22Z
2011-12-27T05:54:11Z
2006
 
Type Article
 
Identifier Organic Letters 8, 1201-1204
1523-7060
http://dx.doi.org/10.1021/ol060041l
http://hdl.handle.net/10054/782
http://dspace.library.iitb.ac.in/xmlui/handle/10054/782
 
Language en