Hydroxyalkylation of conjugated nitroalkenes with activated nonenolizable carbonyl compounds
DSpace at IIT Bombay
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Title |
Hydroxyalkylation of conjugated nitroalkenes with activated nonenolizable carbonyl compounds
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Creator |
DEB, INDUBHUSAN
DADWAL, MAMTA SHAIKH, MOBIN M NAMBOOTHIRI, IRISHI NN |
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Subject |
morita-baylis hilman reaction
acetonitrile activated carbon conjugated |
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Description |
The Morita-Baylis-Hillman reaction of a variety of conjugated nitroalkenes with activated nonenolizable carbonyl compounds such as glyoxylate, trifluoropyruvate, pyruvaldehyde, and ninhydrin in the presence of 40-100 mol % of DMAP in acetonitrile or 100 mol % of imidazole in CHCl3 or THF provided the adducts in decent to good yields. In most cases, the reactions catalyzed by DMAP in acetonitrile were faster and provided the desired MBH adducts in higher yields as compared to the imidazole catalyzed reactions.
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Publisher |
American Chemical Society
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Date |
2009-02-25T12:23:10Z
2011-11-25T17:53:03Z 2011-12-26T13:06:22Z 2011-12-27T05:54:11Z 2009-02-25T12:23:10Z 2011-11-25T17:53:03Z 2011-12-26T13:06:22Z 2011-12-27T05:54:11Z 2006 |
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Type |
Article
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Identifier |
Organic Letters 8, 1201-1204
1523-7060 http://dx.doi.org/10.1021/ol060041l http://hdl.handle.net/10054/782 http://dspace.library.iitb.ac.in/xmlui/handle/10054/782 |
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Language |
en
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