Molecular complexity from aromatics. Cycloaddition of cyclohexa-2,4-dienones, sigmatropic 1,2-acyl shift and ring-closing metathesis: a new, efficient, and stereoselective synthesis of (±)-hirsutic acid C and medium ring carbocycles
DSpace at IIT Bombay
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Title |
Molecular complexity from aromatics. Cycloaddition of cyclohexa-2,4-dienones, sigmatropic 1,2-acyl shift and ring-closing metathesis: a new, efficient, and stereoselective synthesis of (±)-hirsutic acid C and medium ring carbocycles
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Creator |
SINGH, VISHWAKARMA
PAL, SHANTANU TOSH, DILIP K SHAIKH, MOBIN M |
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Subject |
diels-alder reaction
hirsutic acid |
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Description |
A new, stereoselective formal synthesis of hirsutic acid and medium ring carbocyclic systems from salicyl alcohol is described. Cycloaddition between electron deficient partners such as cyclohexa-2,4-dienone and methylmethacrylate, triplet sensitized 1,2-acyl shift and ring-closing metathesis are the key features of our approach.
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Publisher |
Elsevier
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Date |
2009-02-20T05:25:59Z
2011-11-25T17:35:30Z 2011-12-26T13:06:29Z 2011-12-27T05:54:19Z 2009-02-20T05:25:59Z 2011-11-25T17:35:30Z 2011-12-26T13:06:29Z 2011-12-27T05:54:19Z 2007 |
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Type |
Article
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Identifier |
Tetrahedron 63(11), 2446-2454
0040-4020 http://dx.doi.org/10.1016/j.tet.2007.01.006 http://hdl.handle.net/10054/717 http://dspace.library.iitb.ac.in/xmlui/handle/10054/717 |
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Language |
en
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