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Structural diversity through intramolecular cycloaddition and modulation of chemical reactivity in excited state. Synthesis and photoreactions of 3-oxa-tricyclo[5.2.2.01,5]undecenones: novel stereoselective route to oxa-triquinanes and oxa-sterpuranes
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
Structural diversity through intramolecular cycloaddition and modulation of chemical reactivity in excited state. Synthesis and photoreactions of 3-oxa-tricyclo[5.2.2.01,5]undecenones: novel stereoselective route to oxa-triquinanes and oxa-sterpuranes
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| Creator |
SINGH, VISHWAKARMA
ALAM, SQ |
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| Subject |
oxa-triquinanes
oxa-sterpuranes spiroepoxycyclohexa-2,4-dienones |
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| Description |
Synthesis of 11-methyl-3-oxa-tricyclo[5.2.2.01,5]undecenones by intramolecular Diels–Alder reaction of highly labile spiroepoxycyclohexa-2,4-dienones and its photochemical reactions upon triplet (3T) and singlet (1S) excitation leading to a stereoselective route to oxa-triquinane and oxa-sterpurane, respectively, is described.
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| Publisher |
Elsevier
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| Date |
2009-02-20T05:25:50Z
2011-11-25T17:35:00Z 2011-12-26T13:06:29Z 2011-12-27T05:54:19Z 2009-02-20T05:25:50Z 2011-11-25T17:35:00Z 2011-12-26T13:06:29Z 2011-12-27T05:54:19Z 2000 |
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| Type |
Article
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| Identifier |
Bioorganic & Medicinal Chemistry Letters 10(22), 2517-2519
0960-894X http://dx.doi.org/10.1016/S0960-894X(00)00503-5 http://hdl.handle.net/10054/716 http://dspace.library.iitb.ac.in/xmlui/handle/10054/716 |
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| Language |
en
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