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π4s+π2s Cycloaddition between electron deficient π-systems and photoreaction of β,γ-enones: a novel stereoselective entry into angular triquinanes

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Title π4s+π2s Cycloaddition between electron deficient π-systems and photoreaction of β,γ-enones: a novel stereoselective entry into angular triquinanes
 
Creator SINGH, VISHWAKARMA
LAHIRI, SANJOY
 
Subject cycloaddition
chromophore
synthesis
 
Description Cycloaddition of electron deficient partners such as cyclohexa-2,4-dienone and acrylates leading to an efficient synthesis of complex bicyclo[2.2.2]octenones having a β,γ-enone chromophore, and their transformation to angular triquinanes via photoreaction, is described.
 
Publisher Elsevier
 
Date 2009-03-02T12:54:59Z
2011-11-25T18:23:08Z
2011-12-26T13:06:35Z
2011-12-27T05:54:35Z
2009-03-02T12:54:59Z
2011-11-25T18:23:08Z
2011-12-26T13:06:35Z
2011-12-27T05:54:35Z
2003
 
Type Article
 
Identifier Tetrahedron Letters 44(22), 4239-4242
0040-4039
http://dx.doi.org/10.1016/S0040-4039(03)00887-6
http://hdl.handle.net/10054/844
http://dspace.library.iitb.ac.in/xmlui/handle/10054/844
 
Language en