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Mono-, di- and tri-nuclear Ni(II) complexes of N-, O-donor ligands: structural diversity and reactivity

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Title Mono-, di- and tri-nuclear Ni(II) complexes of N-, O-donor ligands: structural diversity and reactivity
 
Creator DEY, MISHTU
RAO, CHEBROLU P
SAARENKETO, PAULI K
KARI RISSANEN
 
Subject mono-, di- and tri-nuclear ni(ii) complexes
urea adduct
pyridine bound mononuclear ni(ii) complex
n-, o-donor molecules
 
Description A series of mono-, di- and tri-nuclear Ni(II) complexes of N, O-donating molecules possessing ---H2C---NH--- and ---HC=N--- moieties have been synthesized and characterized and the structures have been determined by single crystal X-ray diffraction. All these exhibited interesting molecular packing in their crystal lattices. Di-nuclear complexes were found to be cleaved in pyridine to result in mononuclear ones with additional coordinations being provided by pyridine. Di-nuclear complexes were found to form urea adducts as demonstrated based on absorption and vibrational studies.
 
Publisher Elsevier
 
Date 2009-03-02T12:55:27Z
2011-11-25T18:23:38Z
2011-12-26T13:06:44Z
2011-12-27T05:54:43Z
2009-03-02T12:55:27Z
2011-11-25T18:23:38Z
2011-12-26T13:06:44Z
2011-12-27T05:54:43Z
2002
 
Type Article
 
Identifier Inorganic Chemistry Communications 5(11), 924-928
1387-7003
http://dx.doi.org/10.1016/S1387-7003(02)00602-0
http://hdl.handle.net/10054/845
http://dspace.library.iitb.ac.in/xmlui/handle/10054/845
 
Language en