Lanthanide–saccharide chemistry: synthesis and characterisation of Ce(III)–saccharide complexes
DSpace at IIT Bombay
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Title |
Lanthanide–saccharide chemistry: synthesis and characterisation of Ce(III)–saccharide complexes
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Creator |
MUKHOPADHYAY, ANINDITA
KOLEHMAINEN, ERKKI RAO, CHEBROLU P |
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Subject |
metal ions
absorption spectra spectrometers electrochemical analysis |
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Description |
A series of nine Ce(III) complexes has been synthesised with seven different monosaccharides (D-glucose, D-fructose, D-galactose, D-mannose, L-sorbose, D-ribose and D-xylose) and two different disaccharides (D-maltose and L-lactose), and these have been characterised with various analytical, spectral, magnetic and electrochemical techniques. The NMR studies have highlighted some interesting features about the metal-ion-binding pattern of the saccharides. Some additional coordination has been proposed along with the chelating groups in the saccharide molecules, based on the shifts in 13C NMR spectra. On the other hand, solution absorption studies and solid-state magnetic susceptibilities have indicated the contribution from the d-character to the spectral features to some extent.
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Publisher |
Elsevier
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Date |
2009-02-27T11:09:12Z
2011-11-25T18:06:35Z 2011-12-26T13:06:46Z 2011-12-27T05:54:45Z 2009-02-27T11:09:12Z 2011-11-25T18:06:35Z 2011-12-26T13:06:46Z 2011-12-27T05:54:45Z 2000 |
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Type |
Article
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Identifier |
Carbohydrate Research 324(1), 30-37
0008-6215 http://dx.doi.org/10.1016/S0008-6215(99)00277-3 http://hdl.handle.net/10054/811 http://dspace.library.iitb.ac.in/xmlui/handle/10054/811 |
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Language |
en
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