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Synthesis, structure and electrochemistry of acetylide-bridged mixed metal cluster [Fe2(CO)6(μ3-S)2W{(η5-C5H5)W(CO)3(CCPh)}2]

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Title Synthesis, structure and electrochemistry of acetylide-bridged mixed metal cluster [Fe2(CO)6(μ3-S)2W{(η5-C5H5)W(CO)3(CCPh)}2]
 
Creator MATHUR, PRADEEP
MUKHOPADHYAY, SARBANI
MOAWIA, AHMED O
LAHIRI, GOUTAM KUMAR
CHAKRABORTY, SOMA
PURANIK, VEDAVATI G
BHADBHADE, MOHAN M
UMBARKAR, SHUBHANGI B
 
Subject cluster analysis
carbonylation
chalcogenides
electrochemistry
 
Description Thermolysis of a toluene solution containing [Fe2W(CO)10(μ3-S)2] (1) and [(η5-C5H5)W(CO)3(CCPh)] (2), at 80°C yields the mixed metal cluster [Fe2(CO)6(μ3-S)2W{(η5-C5H5)W(CO)3(CCPh)}2] (3). Structure of 3 has been established crystallographically. It consists of a triangular Fe2W unit, each face of which is capped by a sulfido ligand. Each Fe atom bears three carbonyl groups. Two separate molecules of [(η5-C5H5)W(CO)3(CCPh)] are attached to the W atom of the Fe2W core through the acetylide groups.
 
Publisher Elsevier
 
Date 2009-03-09T07:43:58Z
2011-11-25T18:51:12Z
2011-12-26T13:06:51Z
2011-12-27T05:54:50Z
2009-03-09T07:43:58Z
2011-11-25T18:51:12Z
2011-12-26T13:06:51Z
2011-12-27T05:54:50Z
2001
 
Type Article
 
Identifier Journal of Organometallic Chemistry 629(1-2), 160-164
0022-328X
http://dx.doi.org/10.1016/S0022-328X(01)00828-2
http://hdl.handle.net/10054/905
http://dspace.library.iitb.ac.in/xmlui/handle/10054/905
 
Language en