Synthesis, structure and electrochemistry of acetylide-bridged mixed metal cluster [Fe2(CO)6(μ3-S)2W{(η5-C5H5)W(CO)3(CCPh)}2]
DSpace at IIT Bombay
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Title |
Synthesis, structure and electrochemistry of acetylide-bridged mixed metal cluster [Fe2(CO)6(μ3-S)2W{(η5-C5H5)W(CO)3(CCPh)}2]
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Creator |
MATHUR, PRADEEP
MUKHOPADHYAY, SARBANI MOAWIA, AHMED O LAHIRI, GOUTAM KUMAR CHAKRABORTY, SOMA PURANIK, VEDAVATI G BHADBHADE, MOHAN M UMBARKAR, SHUBHANGI B |
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Subject |
cluster analysis
carbonylation chalcogenides electrochemistry |
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Description |
Thermolysis of a toluene solution containing [Fe2W(CO)10(μ3-S)2] (1) and [(η5-C5H5)W(CO)3(CCPh)] (2), at 80°C yields the mixed metal cluster [Fe2(CO)6(μ3-S)2W{(η5-C5H5)W(CO)3(CCPh)}2] (3). Structure of 3 has been established crystallographically. It consists of a triangular Fe2W unit, each face of which is capped by a sulfido ligand. Each Fe atom bears three carbonyl groups. Two separate molecules of [(η5-C5H5)W(CO)3(CCPh)] are attached to the W atom of the Fe2W core through the acetylide groups.
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Publisher |
Elsevier
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Date |
2009-03-09T07:43:58Z
2011-11-25T18:51:12Z 2011-12-26T13:06:51Z 2011-12-27T05:54:50Z 2009-03-09T07:43:58Z 2011-11-25T18:51:12Z 2011-12-26T13:06:51Z 2011-12-27T05:54:50Z 2001 |
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Type |
Article
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Identifier |
Journal of Organometallic Chemistry 629(1-2), 160-164
0022-328X http://dx.doi.org/10.1016/S0022-328X(01)00828-2 http://hdl.handle.net/10054/905 http://dspace.library.iitb.ac.in/xmlui/handle/10054/905 |
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Language |
en
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