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First alkaline earth metal 3-aminobenzoate (3-aba) complex: 1-D polymeric [Ca(3-aba)2(H2O)2]n assembly

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Title First alkaline earth metal 3-aminobenzoate (3-aba) complex: 1-D polymeric [Ca(3-aba)2(H2O)2]n assembly
 
Creator MURUGAVEL, RAMASWAMY
BANERJEE, SUBARNA
 
Subject metal complexes
element
analysis
x-rays
 
Description The reaction of CaCO3 or CaCl2·2H2O with 3-abaH results in the formation of the first alkaline-earth metal complex of 3-abaH [Ca(3-aba)2(H2O)2]n (1) in good yield. The product has been characterized by elemental analysis, IR, UV–vis and 1H NMR spectral studies, TGA and single crystal X-ray diffraction studies. The molecular structure of 1 is made up of 1-D polymeric chains that are hydrogen-bonded to each other. The Ca2+ ion in 1 is surrounded by eight oxygen atoms in a distorted square-antiprismatic geometry.
 
Publisher Elsevier
 
Date 2009-03-09T07:39:08Z
2011-11-25T18:39:40Z
2011-12-26T13:06:54Z
2011-12-27T05:54:52Z
2009-03-09T07:39:08Z
2011-11-25T18:39:40Z
2011-12-26T13:06:54Z
2011-12-27T05:54:52Z
2003
 
Type Article
 
Identifier Inorganic Chemistry Communications 6(7), 810-814
1387-7003
http://dx.doi.org/10.1016/S1387-7003(03)00112-6
http://hdl.handle.net/10054/882
http://dspace.library.iitb.ac.in/xmlui/handle/10054/882
 
Language en