First alkaline earth metal 3-aminobenzoate (3-aba) complex: 1-D polymeric [Ca(3-aba)2(H2O)2]n assembly
DSpace at IIT Bombay
View Archive InfoField | Value | |
Title |
First alkaline earth metal 3-aminobenzoate (3-aba) complex: 1-D polymeric [Ca(3-aba)2(H2O)2]n assembly
|
|
Creator |
MURUGAVEL, RAMASWAMY
BANERJEE, SUBARNA |
|
Subject |
metal complexes
element analysis x-rays |
|
Description |
The reaction of CaCO3 or CaCl2·2H2O with 3-abaH results in the formation of the first alkaline-earth metal complex of 3-abaH [Ca(3-aba)2(H2O)2]n (1) in good yield. The product has been characterized by elemental analysis, IR, UV–vis and 1H NMR spectral studies, TGA and single crystal X-ray diffraction studies. The molecular structure of 1 is made up of 1-D polymeric chains that are hydrogen-bonded to each other. The Ca2+ ion in 1 is surrounded by eight oxygen atoms in a distorted square-antiprismatic geometry.
|
|
Publisher |
Elsevier
|
|
Date |
2009-03-09T07:39:08Z
2011-11-25T18:39:40Z 2011-12-26T13:06:54Z 2011-12-27T05:54:52Z 2009-03-09T07:39:08Z 2011-11-25T18:39:40Z 2011-12-26T13:06:54Z 2011-12-27T05:54:52Z 2003 |
|
Type |
Article
|
|
Identifier |
Inorganic Chemistry Communications 6(7), 810-814
1387-7003 http://dx.doi.org/10.1016/S1387-7003(03)00112-6 http://hdl.handle.net/10054/882 http://dspace.library.iitb.ac.in/xmlui/handle/10054/882 |
|
Language |
en
|
|