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Iron pentacarbonyl assisted photochemical route to 2,5- and 2,6-divinyl-substituted 1,4-benzoquinones from 1-ene-3-ynes
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
Iron pentacarbonyl assisted photochemical route to 2,5- and 2,6-divinyl-substituted 1,4-benzoquinones from 1-ene-3-ynes
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| Creator |
MATHUR, PRADEEP
AVASARE, VIDYA D SHAIKH, MOBIN M |
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| Subject |
benzoquinone
vinyl-substituted ene-yne iron carbonyl photochemical |
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| Description |
Photochemical reaction between the enynes, (Z)-1-methoxybut-1-ene-3-yne, 1 or isopropenyl acetylene, 2 with CO in presence of Fe(CO)5 yields the 2,6- and 2,5-divinyl-substituted 1,4-benzoquinones: 2,6-bis{(Z)-2-methoxyvinyl}-1,4-benzoquinone (3, 42%), 2,5-bis{(Z)-2-methoxyvinyl}-1,4-benzoquinone (4, 31.5%), [{η2,η2:2,6-di(prop-1-en-2-yl)-1,4-benzoquinone}tricarbonyliron] (5, 45%), and {η2,η2:2,5-di(prop-1-en-2-yl)-1,4-benzoquinone}tricarbonyliron] (6, 65%).
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| Publisher |
Elsevier
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| Date |
2009-03-09T07:41:29Z
2011-11-25T18:45:11Z 2011-12-26T13:07:02Z 2011-12-27T05:55:02Z 2009-03-09T07:41:29Z 2011-11-25T18:45:11Z 2011-12-26T13:07:02Z 2011-12-27T05:55:02Z 2008 |
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| Type |
Article
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| Identifier |
Tetrahedron 64(37), 8943-8946
0040-4020 http://dx.doi.org/10.1016/j.tet.2008.06.059 http://hdl.handle.net/10054/893 http://dspace.library.iitb.ac.in/xmlui/handle/10054/893 |
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| Language |
en
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