Formation of 5-phenyl-1,2-dithiole-3-thione from molybdenum dithiopropiolato complexes
DSpace at IIT Bombay
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Title |
Formation of 5-phenyl-1,2-dithiole-3-thione from molybdenum dithiopropiolato complexes
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Creator |
MATHUR, PRADEEP
AVASARE, VIDYA D GHOSH, ABHIJIT K SHAIKH, MOBIN M |
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Subject |
allergies
thermolysis carbonylation |
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Description |
Molybdenum dithiopropiolato complexes, [(η5-C5R4R′)Mo(CO)2(η2-S2CC≡CPh)] (R=H, R=Me 1a, R=R′=H 1b; R=R′=Me 1c) react with trimethylamine-N-oxide (TMNO · 2H2O) under mild thermolysis to form 5-phenyl-1,2-dithiole-3-thione (2). The reaction proceeds through the formation of the oxo-complexes, [(η5-C5R4R′)Mo(O)(η3-S2CC≡CPh)] (R=H, R′=Me 3a, R=R′=H 3b; R=R′=Me 3c). Direct reaction of 3a–c with TMNO · 2H2O under thermolysis also results in formation of 2.
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Publisher |
Elsevier
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Date |
2009-03-05T08:22:34Z
2011-11-25T18:31:39Z 2011-12-26T13:07:04Z 2011-12-27T05:55:06Z 2009-03-05T08:22:34Z 2011-11-25T18:31:39Z 2011-12-26T13:07:04Z 2011-12-27T05:55:06Z 2004 |
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Type |
Article
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Identifier |
Journal of Organometallic Chemistry 689(7), 1325-1327
0022-328X http://dx.doi.org/10.1016/j.jorganchem.2004.01.022 http://hdl.handle.net/10054/866 http://dspace.library.iitb.ac.in/xmlui/handle/10054/866 |
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Language |
en
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