Synthesis, structure and electrochemistry of CO incorporated diruthenium metallacyclic compounds [Ru2(CO)6{μ-η1:η1:η2:η2-1,4-Fc2C5H2O}] and [Ru2(CO)6{μ-η1:η1:η2:η2-1,5-Fc2C5H2O}]
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Title |
Synthesis, structure and electrochemistry of CO incorporated diruthenium metallacyclic compounds [Ru2(CO)6{μ-η1:η1:η2:η2-1,4-Fc2C5H2O}] and [Ru2(CO)6{μ-η1:η1:η2:η2-1,5-Fc2C5H2O}]
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Creator |
MATHUR, PRADEEP
CHATTERJEE, SAURAV DAS, ATANU LAHIRI, GOUTAM KUMAR MAJI, SOMNATH SHAIKH, MOBIN M |
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Subject |
molecular structure
ruthenium substitution reactions synthesis (chemical) |
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Description |
Ferrocenyl substituted ruthenium metallacyclic compounds, [Ru2(CO)6{μ-η1:η1:η2:η2-1,4-Fc2C5H2O}] (1) and [Ru2(CO)6{μ-η1:η1:η2:η2-1,5-Fc2C5H2O}] (2) have been synthesized and structurally characterized. Electrochemical studies for 1 and 2 and the respective quinone derivatives 3 and 4 show weak to no electrochemical coupling at the mixed-valent intermediate state which is dependent on the complex frameworks.
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Publisher |
Elsevier
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Date |
2009-03-05T12:37:26Z
2011-11-25T18:36:40Z 2011-12-26T13:07:05Z 2011-12-27T05:55:07Z 2009-03-05T12:37:26Z 2011-11-25T18:36:40Z 2011-12-26T13:07:05Z 2011-12-27T05:55:07Z 2007 |
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Type |
Article
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Identifier |
Journal of Organometallic Chemistry 692(7), 1601-1607
0022-328X http://dx.doi.org/10.1016/j.jorganchem.2006.12.017 http://hdl.handle.net/10054/876 http://dspace.library.iitb.ac.in/xmlui/handle/10054/876 |
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Language |
en
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