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Synthesis, structure and electrochemistry of CO incorporated diruthenium metallacyclic compounds [Ru2(CO)6{μ-η1:η1:η2:η2-1,4-Fc2C5H2O}] and [Ru2(CO)6{μ-η1:η1:η2:η2-1,5-Fc2C5H2O}]

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Title Synthesis, structure and electrochemistry of CO incorporated diruthenium metallacyclic compounds [Ru2(CO)6{μ-η1:η1:η2:η2-1,4-Fc2C5H2O}] and [Ru2(CO)6{μ-η1:η1:η2:η2-1,5-Fc2C5H2O}]
 
Creator MATHUR, PRADEEP
CHATTERJEE, SAURAV
DAS, ATANU
LAHIRI, GOUTAM KUMAR
MAJI, SOMNATH
SHAIKH, MOBIN M
 
Subject molecular structure
ruthenium
substitution reactions
synthesis (chemical)
 
Description Ferrocenyl substituted ruthenium metallacyclic compounds, [Ru2(CO)6{μ-η1:η1:η2:η2-1,4-Fc2C5H2O}] (1) and [Ru2(CO)6{μ-η1:η1:η2:η2-1,5-Fc2C5H2O}] (2) have been synthesized and structurally characterized. Electrochemical studies for 1 and 2 and the respective quinone derivatives 3 and 4 show weak to no electrochemical coupling at the mixed-valent intermediate state which is dependent on the complex frameworks.
 
Publisher Elsevier
 
Date 2009-03-05T12:37:26Z
2011-11-25T18:36:40Z
2011-12-26T13:07:05Z
2011-12-27T05:55:07Z
2009-03-05T12:37:26Z
2011-11-25T18:36:40Z
2011-12-26T13:07:05Z
2011-12-27T05:55:07Z
2007
 
Type Article
 
Identifier Journal of Organometallic Chemistry 692(7), 1601-1607
0022-328X
http://dx.doi.org/10.1016/j.jorganchem.2006.12.017
http://hdl.handle.net/10054/876
http://dspace.library.iitb.ac.in/xmlui/handle/10054/876
 
Language en