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Synthesis and thermochemical study of ligand substitution reactions of aminobis(phosphines), Ph2P(R)NPPh2, with [Me2Pt(COD)]

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Title Synthesis and thermochemical study of ligand substitution reactions of aminobis(phosphines), Ph2P(R)NPPh2, with [Me2Pt(COD)]
 
Creator BALAKRISHNA, MS
PRIYA, SRINIVASAN
SOMMER, WILLIAM
NOLAN, STEVEN P
 
Subject substitution reactions
thermochemistry
enthalpy
synthesis
 
Description The reactions of aminobis(phosphines), Ph2PN(R)PPh2 (R = H, Me, Et, nPr, nBu, Ph), with Me2Pt(COD) led to the formation of four-membered metallacycles in good yield. The enthalpies of the ligand substitution reactions are measured by the anaerobic solution calorimetry in THF at 30 °C.
 
Publisher Elsevier
 
Date 2009-03-19T07:25:39Z
2011-11-25T19:39:51Z
2011-12-26T13:07:38Z
2011-12-27T05:55:40Z
2009-03-19T07:25:39Z
2011-11-25T19:39:51Z
2011-12-26T13:07:38Z
2011-12-27T05:55:40Z
2005
 
Type Article
 
Identifier Inorganica Chimica Acta 358(9), 2817-2820
0020-1693
http://dx.doi.org/10.1016/j.ica.2005.03.021
http://hdl.handle.net/10054/1007
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1007
 
Language en