Synthesis and thermochemical study of ligand substitution reactions of aminobis(phosphines), Ph2P(R)NPPh2, with [Me2Pt(COD)]
DSpace at IIT Bombay
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Title |
Synthesis and thermochemical study of ligand substitution reactions of aminobis(phosphines), Ph2P(R)NPPh2, with [Me2Pt(COD)]
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Creator |
BALAKRISHNA, MS
PRIYA, SRINIVASAN SOMMER, WILLIAM NOLAN, STEVEN P |
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Subject |
substitution reactions
thermochemistry enthalpy synthesis |
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Description |
The reactions of aminobis(phosphines), Ph2PN(R)PPh2 (R = H, Me, Et, nPr, nBu, Ph), with Me2Pt(COD) led to the formation of four-membered metallacycles in good yield. The enthalpies of the ligand substitution reactions are measured by the anaerobic solution calorimetry in THF at 30 °C.
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Publisher |
Elsevier
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Date |
2009-03-19T07:25:39Z
2011-11-25T19:39:51Z 2011-12-26T13:07:38Z 2011-12-27T05:55:40Z 2009-03-19T07:25:39Z 2011-11-25T19:39:51Z 2011-12-26T13:07:38Z 2011-12-27T05:55:40Z 2005 |
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Type |
Article
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Identifier |
Inorganica Chimica Acta 358(9), 2817-2820
0020-1693 http://dx.doi.org/10.1016/j.ica.2005.03.021 http://hdl.handle.net/10054/1007 http://dspace.library.iitb.ac.in/xmlui/handle/10054/1007 |
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Language |
en
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