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Mono- and di-substituted urea derivatives of cyclodiphosphazane: [ClP(μ-NtBu)2PN(Me)CON(H)Me] and [Me(H)NCON(Me)P(μ-NtBu)]2

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Title Mono- and di-substituted urea derivatives of cyclodiphosphazane: [ClP(μ-NtBu)2PN(Me)CON(H)Me] and [Me(H)NCON(Me)P(μ-NtBu)]2
 
Creator SURESH, D
BALAKRISHNA, MS
MAGUE, JOEL T
 
Subject intermolecular forces
derivatives
molecular structure
x-ray diffraction
 
Description The reaction of cis-[ClP(μ-NtBu)]2 with N,N′-dimethylurea leads to the formation of both mono- and di-substituted derivatives [ClP(μ-NtBu)2P(NMeCON(H)Me)] and [(μ-NtBu)P(NMeCON(H)Me)]2, instead of monomeric, dimeric or higher oligomeric macrocycles. The structure of [ClP(μ-NtBu)2P(NMeCON(H)Me)] shows rare non-bonded P...Cl and intermolecular hydrogen bonding interactions leading to a 2D-sheet like structure.
 
Publisher Elsevier
 
Date 2009-03-20T05:57:32Z
2011-11-25T19:46:52Z
2011-12-26T13:07:41Z
2011-12-27T05:55:43Z
2009-03-20T05:57:32Z
2011-11-25T19:46:52Z
2011-12-26T13:07:41Z
2011-12-27T05:55:43Z
2007
 
Type Article
 
Identifier Tetrahedron Letters 48(13), 2283-2285
0040-4039
http://dx.doi.org/10.1016/j.tetlet.2007.01.164
http://hdl.handle.net/10054/1021
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1021
 
Language en