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Transition metal (Group 6, Ru and Group 10) derivatives of aminophosphines, Ph2PN(H)R (R=Ph, C6H11)
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
Transition metal (Group 6, Ru and Group 10) derivatives of aminophosphines, Ph2PN(H)R (R=Ph, C6H11)
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| Creator |
SRINIVASAN, PRASHANT
BALAKRISHNA, MS MAGUE, JOEL T |
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| Subject |
derivatives
transition metals x-ray crystallography synthesis |
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| Description |
The reactions of aminophosphines with Group 6 metal carbonyls afford both mono-substituted and disubstituted complexes. The reaction of Ph2PN(H)C6H11 with molybdenum tetracarbonyl derivative gives a mixture of cis and trans-isomers. The reaction of Ph2PN(H)Ph with Pd(COD)Cl2 leads to the P-N bond cleavage to give chloro bridged dimer, [Pd(PPh2O)(PPh2OH)(μ-Cl)]2, whereas with Pt(COD)Cl2, disubstituted cis-[PtCl2{PPh2N(H)R}2]2 was obtained. The reaction of Ph2PN(H)C6H11 with RuCl2(DMSO)4 or RuCl2(PPh3)3 leads to the formation of ionic complex, [RuCl{Ph2PN(H)C6H11}3]Cl.
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| Publisher |
Elsevier
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| Date |
2009-03-20T06:00:09Z
2011-11-25T19:56:54Z 2011-12-26T13:07:42Z 2011-12-27T05:55:44Z 2009-03-20T06:00:09Z 2011-11-25T19:56:54Z 2011-12-26T13:07:42Z 2011-12-27T05:55:44Z 2003 |
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| Type |
Article
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| Identifier |
Journal of Organometallic Chemistry 679(1), 116-124
0022-328X http://dx.doi.org/10.1016/S0022-328X(03)00543-6 http://hdl.handle.net/10054/1041 http://dspace.library.iitb.ac.in/xmlui/handle/10054/1041 |
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| Language |
en
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