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TRINUCLEAR AND TETRANUCLEAR IRON RUTHENIUM CARBONYL CLUSTERS STABILIZED BY BRIDGING SELENIUM LIGANDS
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
TRINUCLEAR AND TETRANUCLEAR IRON RUTHENIUM CARBONYL CLUSTERS STABILIZED BY BRIDGING SELENIUM LIGANDS
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| Creator |
MATHUR, P
HOSSAIN, MM RASHID, RS |
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| Subject |
reactivity
fe3(mu-3-te)2(co)9 te se |
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| Description |
At room temperature, Fe2(CO)6(mu-Se2) reacts with Ru3(CO)12 to form Fe2Ru3(CO)17(mu4-Se)(mu3-Se), and with Ru(CO)4(C2H4) to form Fe2Ru(CO)9(mu3-Se)2. The latter reacts with Fe(CO)5 under visible light irradiation to give Fe3Ru(CO)11(mu4-Se)2, and with RU(CO)4(C2H4) to form Fe2Ru2(CO)11(mu4-Se)2. Visible light irradiation of a solution containing Fe3(CO)9(mu3-Se)2 and Fe(CO)5 yields Fe4(CO)11(mu4-Se)2. A solution containing Fe3(CO)9(mu3-Se)2 and Ru(CO)4(C2H4) at room temperature with stirring yielded Fe3Ru(CO)11(mu4-Se)2.
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| Publisher |
ELSEVIER SCIENCE SA LAUSANNE
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| Date |
2011-07-29T18:02:16Z
2011-12-26T12:48:50Z 2011-12-27T05:55:45Z 2011-07-29T18:02:16Z 2011-12-26T12:48:50Z 2011-12-27T05:55:45Z 1993 |
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| Type |
Article
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| Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 460(1), 83-86
0022-328X http://dx.doi.org/10.1016/0022-328X(93)80361-E http://dspace.library.iitb.ac.in/xmlui/handle/10054/7784 http://hdl.handle.net/10054/7784 |
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| Language |
en
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