Transition metal chemistry of phosphorus based ligands: synthesis and transition metal chemistry of N,N′-dimethyl,-bis(diphenylphosphino)ethylenediamine. The crystal and molecular structure of [ReBr(CO)3{Ph2PN(Me)CH2CH2(Me)NPPh2}]
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Title |
Transition metal chemistry of phosphorus based ligands: synthesis and transition metal chemistry of N,N′-dimethyl,-bis(diphenylphosphino)ethylenediamine. The crystal and molecular structure of [ReBr(CO)3{Ph2PN(Me)CH2CH2(Me)NPPh2}]
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Creator |
BALAKRISHNA, MS
WALAWALKAR, MRINALINI G |
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Subject |
transition metal compounds
derivatives crystals chemistry |
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Description |
The bis(phosphine), Ph2PN(CH3)CH2CH2N(CH3)PPh2 reacts with Group 6 metal carbonyl derivatives, [ReBr(CO)3(NCMe)2] and [MCl2(COD)] (M=Pd or Pt) to give the corresponding seven-membered chelate complexes. The compounds have been characterized by elemental analysis, IR and NMR spectroscopic data. The structure of the rhenium complex, [ReBr(CO)3{Ph2PN(CH3)CH2CH2(CH3)NPPh2}] has been confirmed by X-ray crystallography.
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Publisher |
Elsevier
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Date |
2009-03-19T07:25:11Z
2011-11-25T19:37:50Z 2011-12-26T13:07:43Z 2011-12-27T05:55:45Z 2009-03-19T07:25:11Z 2011-11-25T19:37:50Z 2011-12-26T13:07:43Z 2011-12-27T05:55:45Z 2001 |
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Type |
Article
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Identifier |
Journal of Organometallic Chemistry 628(1), 76-80
0022-328X http://dx.doi.org/10.1016/S0022-328X(01)00764-1 http://hdl.handle.net/10054/1003 http://dspace.library.iitb.ac.in/xmlui/handle/10054/1003 |
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Language |
en
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