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Disulfide and diselenides of bis(phosphines) derived from N,N′-substituted ethylenediamines. The crystal and molecular structure of Ph2P(S)N(Ph)CH2CH2N(Ph)P(S)Ph2
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
Disulfide and diselenides of bis(phosphines) derived from N,N′-substituted ethylenediamines. The crystal and molecular structure of Ph2P(S)N(Ph)CH2CH2N(Ph)P(S)Ph2
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| Creator |
BALAKRISHNA, MS
MAGUE, JOEL T |
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| Subject |
spectra
derivatives x-ray crystallography crystal structure |
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| Description |
The reactions of bis(diphosphino)ethylenediamine derivatives, [Ph2PN(R)CH2]2 (R=CH3, CH2Ph or Ph) with elemental sulfur and selenium afford the corresponding disulfide or diselenide derivatives in good yield. All compounds have been characterized by elemental analysis, NMR (31P and 1H) and IR spectroscopic data. The structure of one of the disulfide derivative, [Ph2P(S)N(Ph)CH2]2 is determined by X-ray crystallography.
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| Publisher |
Elsevier
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| Date |
2009-03-20T05:58:10Z
2011-11-25T19:49:23Z 2011-12-26T13:07:51Z 2011-12-27T05:55:49Z 2009-03-20T05:58:10Z 2011-11-25T19:49:23Z 2011-12-26T13:07:51Z 2011-12-27T05:55:49Z 2001 |
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| Type |
Article
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| Identifier |
Polyhedron 20(18), 2421-2424
0277-5387 http://dx.doi.org/10.1016/S0277-5387(01)00839-7 http://hdl.handle.net/10054/1026 http://dspace.library.iitb.ac.in/xmlui/handle/10054/1026 |
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| Language |
en
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