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Synthesis, spectroscopic study and X-ray crystal structure of unsymmetrical bis(phosphine)-platinum complex, [PtCl2{η2-Ph2POCH2CH2N(CH3)PPh2]
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
Synthesis, spectroscopic study and X-ray crystal structure of unsymmetrical bis(phosphine)-platinum complex, [PtCl2{η2-Ph2POCH2CH2N(CH3)PPh2]
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| Creator |
BALAKRISHNA, MS
MCDONALD, ROBERT |
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| Subject |
spectroscopic analysis
x-ray crystallography experimental synthesis |
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| Description |
The bis(phosphine), Ph2POCH2CH2N(CH3)PPh2(1) reacts with [Pt(COD)Cl2] to give seven-membered cis-chelated complex 2. The complex was characterized by elemental analysis, IR, and NMR spectroscopic methods of which the 31P{1H} NMR data is very informative and allows the direct measure of the P–P coupling through metal centers otherwise can not be seen in the free ligand as the two phosphorus centers are five-bonds apart. The structure of the platinum(II) complex was determined by X-ray crystallography.
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| Publisher |
Elsevier
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| Date |
2009-03-20T05:57:07Z
2011-11-25T19:45:22Z 2011-12-26T13:07:54Z 2011-12-27T05:55:57Z 2009-03-20T05:57:07Z 2011-11-25T19:45:22Z 2011-12-26T13:07:54Z 2011-12-27T05:55:57Z 2002 |
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| Type |
Article
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| Identifier |
Inorganic Chemistry Communications 5(10), 782-786
1387-7003 http://dx.doi.org/10.1016/S1387-7003(02)00558-0 http://hdl.handle.net/10054/1018 http://dspace.library.iitb.ac.in/xmlui/handle/10054/1018 |
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| Language |
en
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