Silicon based phosphines with P–Si–P, P–C–Si–C–P and P–O–Si–O–P linkages and their coordination chemistry and catalytic applications
DSpace at IIT Bombay
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Title |
Silicon based phosphines with P–Si–P, P–C–Si–C–P and P–O–Si–O–P linkages and their coordination chemistry and catalytic applications
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Creator |
BALAKRISHNA, MS
CHANDRASEKARAN, P GEORGE, PP |
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Subject |
single crystals
x-ray diffraction spectroscopic analysis catalysis |
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Description |
The synthesis and coordination chemistry of bis- and tris(phosphines) with P–Si–P, P–O–Si–O–P and P–C–Si–C–P linkages is reviewed. The catalytic reactions involving organometallic complexes of silylphosphines are presented. The silylbis- and tris(phosphines) show remarkable versatility in their coordination behavior with transition metals. The improved solubility of these ligands and their complexes facilitated spectroscopic studies to compliment the structural information obtained via single crystal X-ray diffraction studies. The syntheses and reactivity of other related acyclic and cyclic systems with P–N–Si–N–P and P–aryl–Si-aryl–P linkages are also briefly described.
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Publisher |
Elsevier
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Date |
2009-03-19T07:25:54Z
2011-11-25T19:40:51Z 2011-12-26T13:07:57Z 2011-12-27T05:55:58Z 2009-03-19T07:25:54Z 2011-11-25T19:40:51Z 2011-12-26T13:07:57Z 2011-12-27T05:55:58Z 2003 |
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Type |
Article
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Identifier |
Coordination Chemistry Reviews 241(1-2), 87-117
0010-8545 http://dx.doi.org/10.1016/S0010-8545(03)00018-3 http://hdl.handle.net/10054/1009 http://dspace.library.iitb.ac.in/xmlui/handle/10054/1009 |
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Language |
en
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