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Silicon based phosphines with P–Si–P, P–C–Si–C–P and P–O–Si–O–P linkages and their coordination chemistry and catalytic applications

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Title Silicon based phosphines with P–Si–P, P–C–Si–C–P and P–O–Si–O–P linkages and their coordination chemistry and catalytic applications
 
Creator BALAKRISHNA, MS
CHANDRASEKARAN, P
GEORGE, PP
 
Subject single crystals
x-ray diffraction
spectroscopic analysis
catalysis
 
Description The synthesis and coordination chemistry of bis- and tris(phosphines) with P–Si–P, P–O–Si–O–P and P–C–Si–C–P linkages is reviewed. The catalytic reactions involving organometallic complexes of silylphosphines are presented. The silylbis- and tris(phosphines) show remarkable versatility in their coordination behavior with transition metals. The improved solubility of these ligands and their complexes facilitated spectroscopic studies to compliment the structural information obtained via single crystal X-ray diffraction studies. The syntheses and reactivity of other related acyclic and cyclic systems with P–N–Si–N–P and P–aryl–Si-aryl–P linkages are also briefly described.
 
Publisher Elsevier
 
Date 2009-03-19T07:25:54Z
2011-11-25T19:40:51Z
2011-12-26T13:07:57Z
2011-12-27T05:55:58Z
2009-03-19T07:25:54Z
2011-11-25T19:40:51Z
2011-12-26T13:07:57Z
2011-12-27T05:55:58Z
2003
 
Type Article
 
Identifier Coordination Chemistry Reviews 241(1-2), 87-117
0010-8545
http://dx.doi.org/10.1016/S0010-8545(03)00018-3
http://hdl.handle.net/10054/1009
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1009
 
Language en