First examples of methylene insertion into the phosphorus(III)–nitrogen bond
DSpace at IIT Bombay
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Title |
First examples of methylene insertion into the phosphorus(III)–nitrogen bond
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Creator |
SRINIVASAN, PRIYA
BALAKRISHNA, MS MAGUE, JOEL T |
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Subject |
insertion
phosphinoamine phosphine oxide paraformaldehyde |
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Description |
The reaction of N-substituted phosphinous amides with paraformaldehyde leads to methylene insertion into the P–N bond, followed by the oxidation of phosphorus from P(III) to P(V) state. The product, Ph2P(O)CH2NHPh was characterised by a single-crystal X-ray diffraction study. The reaction not only depends on the acidic proton on the nitrogen, but also on the oxidation state of phosphorus and it is considered to proceed through Staudinger–Wittig pathway.
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Publisher |
Elsevier
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Date |
2009-03-20T05:56:57Z
2011-11-25T19:44:52Z 2011-12-26T13:08:00Z 2011-12-27T05:56:00Z 2009-03-20T05:56:57Z 2011-11-25T19:44:52Z 2011-12-26T13:08:00Z 2011-12-27T05:56:00Z 2001 |
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Type |
Article
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Identifier |
Inorganic Chemistry Communications 4(8), 437-440
1387-7003 http://dx.doi.org/10.1016/S1387-7003(01)00222-2 http://hdl.handle.net/10054/1017 http://dspace.library.iitb.ac.in/xmlui/handle/10054/1017 |
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Language |
en
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