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First examples of methylene insertion into the phosphorus(III)–nitrogen bond

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Title First examples of methylene insertion into the phosphorus(III)–nitrogen bond
 
Creator SRINIVASAN, PRIYA
BALAKRISHNA, MS
MAGUE, JOEL T
 
Subject insertion
phosphinoamine
phosphine oxide
paraformaldehyde
 
Description The reaction of N-substituted phosphinous amides with paraformaldehyde leads to methylene insertion into the P–N bond, followed by the oxidation of phosphorus from P(III) to P(V) state. The product, Ph2P(O)CH2NHPh was characterised by a single-crystal X-ray diffraction study. The reaction not only depends on the acidic proton on the nitrogen, but also on the oxidation state of phosphorus and it is considered to proceed through Staudinger–Wittig pathway.
 
Publisher Elsevier
 
Date 2009-03-20T05:56:57Z
2011-11-25T19:44:52Z
2011-12-26T13:08:00Z
2011-12-27T05:56:00Z
2009-03-20T05:56:57Z
2011-11-25T19:44:52Z
2011-12-26T13:08:00Z
2011-12-27T05:56:00Z
2001
 
Type Article
 
Identifier Inorganic Chemistry Communications 4(8), 437-440
1387-7003
http://dx.doi.org/10.1016/S1387-7003(01)00222-2
http://hdl.handle.net/10054/1017
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1017
 
Language en