Hydrogenation of α-acetamidocinnamic acid with polystyrene-supported rhodium catalysts
DSpace at IIT Bombay
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Title |
Hydrogenation of α-acetamidocinnamic acid with polystyrene-supported rhodium catalysts
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Creator |
BHADURI, SUMIT
LAHIRI, GOUTAM KUMAR MUNSHI, PRADIP |
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Subject |
computer simulation
thermal effects enthalpy distillation |
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Description |
Divinylbenzene cross-linked chloromethylated polystyrene has been functionalised with cinchonine, ephedrine, 3S,4S-N-benzylpyrrolidinediol and four achiral amines. The resins have been used as supports for anchoring [Rh(CO)2Cl2]−. The polymer-supported complex has been tested as a catalyst precursor for the hydrogenation of α-acetamidocinnamic acid. Highest rate and modest enantioselectivity are obtained with cinchonine functionalized polymer-supported complex. This complex also undergoes reversible decarbonylation.
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Publisher |
Elsevier
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Date |
2009-03-23T05:11:35Z
2011-11-25T20:03:25Z 2011-12-26T13:08:00Z 2011-12-27T05:56:01Z 2009-03-23T05:11:35Z 2011-11-25T20:03:25Z 2011-12-26T13:08:00Z 2011-12-27T05:56:01Z 2000 |
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Type |
Article
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Identifier |
Journal of Organometallic Chemistry 606(2), 151-155
0022-328X http://dx.doi.org/10.1016/S0022-328X(00)00334-X http://hdl.handle.net/10054/1054 http://dspace.library.iitb.ac.in/xmlui/handle/10054/1054 |
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Language |
en
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