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Hydrogenation of α-acetamidocinnamic acid with polystyrene-supported rhodium catalysts

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Field Value
 
Title Hydrogenation of α-acetamidocinnamic acid with polystyrene-supported rhodium catalysts
 
Creator BHADURI, SUMIT
LAHIRI, GOUTAM KUMAR
MUNSHI, PRADIP
 
Subject computer simulation
thermal effects
enthalpy
distillation
 
Description Divinylbenzene cross-linked chloromethylated polystyrene has been functionalised with cinchonine, ephedrine, 3S,4S-N-benzylpyrrolidinediol and four achiral amines. The resins have been used as supports for anchoring [Rh(CO)2Cl2]−. The polymer-supported complex has been tested as a catalyst precursor for the hydrogenation of α-acetamidocinnamic acid. Highest rate and modest enantioselectivity are obtained with cinchonine functionalized polymer-supported complex. This complex also undergoes reversible decarbonylation.
 
Publisher Elsevier
 
Date 2009-03-23T05:11:35Z
2011-11-25T20:03:25Z
2011-12-26T13:08:00Z
2011-12-27T05:56:01Z
2009-03-23T05:11:35Z
2011-11-25T20:03:25Z
2011-12-26T13:08:00Z
2011-12-27T05:56:01Z
2000
 
Type Article
 
Identifier Journal of Organometallic Chemistry 606(2), 151-155
0022-328X
http://dx.doi.org/10.1016/S0022-328X(00)00334-X
http://hdl.handle.net/10054/1054
http://dspace.library.iitb.ac.in/xmlui/handle/10054/1054
 
Language en