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Synthesis of a new fluorescent macrocyclic alpha-amino acid derivative via tandem cross-enyne/ring-closing metathesis cascade catalyzed by ruthenium based catalysts

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Title Synthesis of a new fluorescent macrocyclic alpha-amino acid derivative via tandem cross-enyne/ring-closing metathesis cascade catalyzed by ruthenium based catalysts
 
Creator KOTHA, S
BANSAL, D
SINGH, K
BANERJEE, S
 
Subject RING
AGENTS
Ruthenium based catalysts
Tandem metathesis
Fluorescent alpha-amino acid (AAA) derivatives
Macrocyclic alpha-amino acid
 
Description A simple methodology to a unique macrocyclic alpha-amino acid (AAA) derivative involving three step synthetic sequence has been reported. In addition, various ruthenium based catalysts were studied to enhance the selectivity of the desired macrocyclic AAA derivative 6. The fluorescence behavior of these AAA derivatives 5 and 6 indicate their potential applications in biological sciences as biomarkers, ion sensors and peptidomimetics. (C) 2011 Elsevier B.V. All rights reserved.
 
Publisher ELSEVIER SCIENCE SA
 
Date 2012-01-20T10:09:14Z
2012-01-20T10:09:14Z
2011
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY,696(9)1856-1860
0022-328X
http://dx.doi.org/10.1016/j.jorganchem.2011.02.019
http://dspace.library.iitb.ac.in/jspui/handle/100/13822
 
Language English