Synthesis of a new fluorescent macrocyclic alpha-amino acid derivative via tandem cross-enyne/ring-closing metathesis cascade catalyzed by ruthenium based catalysts
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Title |
Synthesis of a new fluorescent macrocyclic alpha-amino acid derivative via tandem cross-enyne/ring-closing metathesis cascade catalyzed by ruthenium based catalysts
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Creator |
KOTHA, S
BANSAL, D SINGH, K BANERJEE, S |
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Subject |
RING
AGENTS Ruthenium based catalysts Tandem metathesis Fluorescent alpha-amino acid (AAA) derivatives Macrocyclic alpha-amino acid |
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Description |
A simple methodology to a unique macrocyclic alpha-amino acid (AAA) derivative involving three step synthetic sequence has been reported. In addition, various ruthenium based catalysts were studied to enhance the selectivity of the desired macrocyclic AAA derivative 6. The fluorescence behavior of these AAA derivatives 5 and 6 indicate their potential applications in biological sciences as biomarkers, ion sensors and peptidomimetics. (C) 2011 Elsevier B.V. All rights reserved.
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Publisher |
ELSEVIER SCIENCE SA
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Date |
2012-01-20T10:09:14Z
2012-01-20T10:09:14Z 2011 |
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Type |
Article
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Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY,696(9)1856-1860
0022-328X http://dx.doi.org/10.1016/j.jorganchem.2011.02.019 http://dspace.library.iitb.ac.in/jspui/handle/100/13822 |
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Language |
English
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