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Synthesis and structure of new Schiff base derivatives obtained from 2-(formylphenyl)mercury bromide

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Title Synthesis and structure of new Schiff base derivatives obtained from 2-(formylphenyl)mercury bromide
 
Creator BALIGAR, RS
SHARMA, S
SINGH, HB
BUTCHER, RJ
 
Subject RAY CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE
COMPLEXES
MERCURY
CHLORIDE
METALLAMACROCYCLE
RADII
BOND
VAN
Organomercury
Mercuration
Metallamacrocycle
Intramolecular interaction
Anion binding
 
Description Reactions of (2-formylphenyl)mercury(II) bromide 10 with primary amines give mono-, bis- and tris-Schiff base derivatives (11-18). Structures of the synthesized compounds show the presence of five-membered intramolecular Hg center dot center dot center dot N interaction. Luminescence studies of the compounds have been performed. Attempts to use the synthesized compounds for binding neutral donor molecules or fluoride ions were unsuccessful.
 
Publisher ELSEVIER SCIENCE SA
 
Date 2012-01-20T10:10:45Z
2012-01-20T10:10:45Z
2011
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY,696(18)3015-3022
0022-328X
http://dx.doi.org/10.1016/j.jorganchem.2011.06.001
http://dspace.library.iitb.ac.in/jspui/handle/100/13825
 
Language English