Synthesis and structure of new Schiff base derivatives obtained from 2-(formylphenyl)mercury bromide
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Title |
Synthesis and structure of new Schiff base derivatives obtained from 2-(formylphenyl)mercury bromide
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Creator |
BALIGAR, RS
SHARMA, S SINGH, HB BUTCHER, RJ |
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Subject |
RAY CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE COMPLEXES MERCURY CHLORIDE METALLAMACROCYCLE RADII BOND VAN Organomercury Mercuration Metallamacrocycle Intramolecular interaction Anion binding |
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Description |
Reactions of (2-formylphenyl)mercury(II) bromide 10 with primary amines give mono-, bis- and tris-Schiff base derivatives (11-18). Structures of the synthesized compounds show the presence of five-membered intramolecular Hg center dot center dot center dot N interaction. Luminescence studies of the compounds have been performed. Attempts to use the synthesized compounds for binding neutral donor molecules or fluoride ions were unsuccessful.
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Publisher |
ELSEVIER SCIENCE SA
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Date |
2012-01-20T10:10:45Z
2012-01-20T10:10:45Z 2011 |
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Type |
Article
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Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY,696(18)3015-3022
0022-328X http://dx.doi.org/10.1016/j.jorganchem.2011.06.001 http://dspace.library.iitb.ac.in/jspui/handle/100/13825 |
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Language |
English
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