A Concise Stereoselective Synthesis of the Tetracyclic Naphthoquinone (-)-Isagarin
DSpace at IIT Bombay
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Title |
A Concise Stereoselective Synthesis of the Tetracyclic Naphthoquinone (-)-Isagarin
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Creator |
FERNANDES, RA
INGLE, AB |
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Subject |
ENANTIOSELECTIVE SYNTHESIS
PENTAS-LONGIFLORA CARBENE COMPLEXES ORGANIC-SYNTHESIS (+)-NOCARDIONE B FORMAL SYNTHESIS ISAGARIN (+)-ALLO-ELEUTHERIN (+)-ELEUTHERIN BENZANNULATION Natural products Fused-ring systems Carbenes Annulation Ketalization |
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Description |
A concise stereoselective synthesis of the tetracyclic naphthoquinone natural product (-)-isagarin has been completed in seven steps from known alkyne 5 (obtained from D-mannitol) by using Dotz benzannulation and intramolecular stereospecific dioxabicyclic ketal formation as key steps.
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Publisher |
WILEY-BLACKWELL
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Date |
2012-06-26T04:52:29Z
2012-06-26T04:52:29Z 2011 |
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Type |
Article
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Identifier |
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,(33)6624-6627
1434-193X http://dx.doi.org/10.1002/ejoc.201101279 http://dspace.library.iitb.ac.in/jspui/handle/100/13910 |
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Language |
English
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