Synthesis and structure of new Schiff base derivatives obtained from 2-(formylphenyl)mercury bromide
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Title |
Synthesis and structure of new Schiff base derivatives obtained from 2-(formylphenyl)mercury bromide
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Creator |
BALIGAR, RS
SHARMA, S SINGH, HB BUTCHER, RJ |
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Subject |
RAY CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE COMPLEXES MERCURY CHLORIDE METALLAMACROCYCLE RADII BOND VAN Organomercury Mercuration Metallamacrocycle Intramolecular interaction Anion binding |
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Description |
Reactions of (2-formylphenyl)mercury(II) bromide 10 with primary amines give mono-, bis- and tris-Schiff base derivatives (11-18). Structures of the synthesized compounds show the presence of five-membered intramolecular Hg center dot center dot center dot N interaction. Luminescence studies of the compounds have been performed. Attempts to use the synthesized compounds for binding neutral donor molecules or fluoride ions were unsuccessful. (C) 2011 Elsevier B. V. All rights reserved.
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Publisher |
ELSEVIER SCIENCE SA
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Date |
2012-06-26T07:27:36Z
2012-06-26T07:27:36Z 2011 |
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Type |
Article
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Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY,696(18)3015-3022
0022-328X http://dx.doi.org/10.1016/j.jorganchem.2011.06.001 http://dspace.library.iitb.ac.in/jspui/handle/100/14134 |
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Language |
English
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