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Synthesis and structure of new Schiff base derivatives obtained from 2-(formylphenyl)mercury bromide

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Title Synthesis and structure of new Schiff base derivatives obtained from 2-(formylphenyl)mercury bromide
 
Creator BALIGAR, RS
SHARMA, S
SINGH, HB
BUTCHER, RJ
 
Subject RAY CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE
COMPLEXES
MERCURY
CHLORIDE
METALLAMACROCYCLE
RADII
BOND
VAN
Organomercury
Mercuration
Metallamacrocycle
Intramolecular interaction
Anion binding
 
Description Reactions of (2-formylphenyl)mercury(II) bromide 10 with primary amines give mono-, bis- and tris-Schiff base derivatives (11-18). Structures of the synthesized compounds show the presence of five-membered intramolecular Hg center dot center dot center dot N interaction. Luminescence studies of the compounds have been performed. Attempts to use the synthesized compounds for binding neutral donor molecules or fluoride ions were unsuccessful. (C) 2011 Elsevier B. V. All rights reserved.
 
Publisher ELSEVIER SCIENCE SA
 
Date 2012-06-26T07:27:36Z
2012-06-26T07:27:36Z
2011
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY,696(18)3015-3022
0022-328X
http://dx.doi.org/10.1016/j.jorganchem.2011.06.001
http://dspace.library.iitb.ac.in/jspui/handle/100/14134
 
Language English