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Synthetic approach to cis and trans-decalins via Diels-Alder reaction and ring-closing metathesis as key steps: further extension to dioxapropellane derivative by ring-closing metathesis

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Title Synthetic approach to cis and trans-decalins via Diels-Alder reaction and ring-closing metathesis as key steps: further extension to dioxapropellane derivative by ring-closing metathesis
 
Creator KOTHA, S
CHAVAN, AS
DIPAK, MK
 
Subject OLEFIN-METATHESIS
CATALYTIC METATHESIS
ANTIBIOTIC BRANIMYCIN
ALKENE METATHESIS
VICINAL DIESTERS
NOBEL LECTURE
PROPELLANES
ALPHA,OMEGA-DIHALIDES
MACROCYCLES
CARBON
Diels-Alder reaction
Ring-closing metathesis
Decalin
Propellane
Hydrogenation
 
Description 9,10-Substituted cis and trans-decalins were synthesized by a simple route using the Diels-Alder reaction and ring-closing metathesis (RCM) as key steps. Later, the cis-decalin system has been extended to 3,8-dioxa[8.4.4]propellane derivative by RCM sequence as a key step. (C) 2010 Elsevier Ltd. All rights reserved.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2012-06-26T08:37:40Z
2012-06-26T08:37:40Z
2011
 
Type Article
 
Identifier TETRAHEDRON,67(2)501-504
0040-4020
http://dx.doi.org/10.1016/j.tet.2010.10.080
http://dspace.library.iitb.ac.in/jspui/handle/100/14200
 
Language English