A Dotz benzannulation route to the enantioselective synthesis of (-)- and (+)-juglomycin A
DSpace at IIT Bombay
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Title |
A Dotz benzannulation route to the enantioselective synthesis of (-)- and (+)-juglomycin A
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Creator |
FERNANDES, RA
CHAVAN, VP |
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Subject |
ENANTIODIVERGENT TOTAL SYNTHESES
FRENOLICIN-B ASYMMETRIC DIHYDROXYLATION CRISAMICIN-A EFFICIENT SYNTHESIS KALAFUNGIN ANTIBIOTICS ACIDS (-)-NANAOMYCIN-D DEOXYFRENOLICIN |
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Description |
Two synthetic routes based on a Dotz benzannulation toward the enantioselective synthesis of naphthoquinone antibiotics (-)- and (+)-juglomycin A are described. The stereoinducing step is based on asymmetric dihydroxylation. The syntheses are completed in seven to eight steps from Fischer carbene 12. (C) 2011 Elsevier Ltd. All rights reserved.
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Publisher |
PERGAMON-ELSEVIER SCIENCE LTD
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Date |
2012-06-26T08:40:10Z
2012-06-26T08:40:10Z 2011 |
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Type |
Article
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Identifier |
TETRAHEDRON-ASYMMETRY,22(12)1312-1319
0957-4166 http://dx.doi.org/10.1016/j.tetasy.2011.07.018 http://dspace.library.iitb.ac.in/jspui/handle/100/14205 |
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Language |
English
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