Boron Complexes of Oxasmaragdyrin, a Core-Modified Expanded Porphyrin
DSpace at IIT Bombay
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Title |
Boron Complexes of Oxasmaragdyrin, a Core-Modified Expanded Porphyrin
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Creator |
RAO, MR
RAVIKANTH, M |
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Subject |
ELECTROCHEMICAL PROPERTIES
CHEMISTRY RECEPTORS ANION SMARAGDYRINS SAPPHYRIN BODIPY LIGAND DYES |
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Description |
We report the synthesis of first examples of BF(2) and B(OR)(2) complexes of oxasmaragdyrin, the expanded core-modified porphyrin, in decent yields under very simple reaction conditions at room temperature. The boron complexation of oxasmaragdyrin alters the electronic properties of the macrocycle significantly as evident by various spectroscopic techniques. Our preliminary studies indicated that the B(OH)(2)-smaragdyrin complex can act as a selective neutral fluoride ion sensor.
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Publisher |
AMER CHEMICAL SOC
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Date |
2012-06-26T08:57:15Z
2012-06-26T08:57:15Z 2011 |
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Type |
Article
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Identifier |
JOURNAL OF ORGANIC CHEMISTRY,76(9)3582-3587
0022-3263 http://dx.doi.org/10.1021/jo200295b http://dspace.library.iitb.ac.in/jspui/handle/100/14239 |
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Language |
English
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