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Boron Complexes of Oxasmaragdyrin, a Core-Modified Expanded Porphyrin

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Field Value
 
Title Boron Complexes of Oxasmaragdyrin, a Core-Modified Expanded Porphyrin
 
Creator RAO, MR
RAVIKANTH, M
 
Subject ELECTROCHEMICAL PROPERTIES
CHEMISTRY
RECEPTORS
ANION
SMARAGDYRINS
SAPPHYRIN
BODIPY
LIGAND
DYES
 
Description We report the synthesis of first examples of BF(2) and B(OR)(2) complexes of oxasmaragdyrin, the expanded core-modified porphyrin, in decent yields under very simple reaction conditions at room temperature. The boron complexation of oxasmaragdyrin alters the electronic properties of the macrocycle significantly as evident by various spectroscopic techniques. Our preliminary studies indicated that the B(OH)(2)-smaragdyrin complex can act as a selective neutral fluoride ion sensor.
 
Publisher AMER CHEMICAL SOC
 
Date 2012-06-26T08:57:15Z
2012-06-26T08:57:15Z
2011
 
Type Article
 
Identifier JOURNAL OF ORGANIC CHEMISTRY,76(9)3582-3587
0022-3263
http://dx.doi.org/10.1021/jo200295b
http://dspace.library.iitb.ac.in/jspui/handle/100/14239
 
Language English