Synthesis of Sterically Crowded Polyarylated Boron-Dipyrromethenes
DSpace at IIT Bombay
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Title |
Synthesis of Sterically Crowded Polyarylated Boron-Dipyrromethenes
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Creator |
LAKSHMI, V
RAVIKANTH, M |
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Subject |
QUANTUM-CHEMICAL CALCULATIONS
FLUORESCENT BODIPY DYES CRYSTAL-STRUCTURE ELECTROCHEMISTRY DERIVATIVES SPECTROSCOPY PHOTOPHYSICS SEPARATION COMPLEXES CHEMISTRY |
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Description |
A rapid synthetic route for polyarylated boron-dipyrromethenes using hexabromo boron-dipyrromethene as the key synthon is described. The X-ray structure revealed that the polyarylated BODIPY adopts a propeller-like conformation. These compounds exhibit red-shifted absorption and fluorescence bands with decent quantum yields and reversible oxidation and reduction waves when compared to unsubstituted boron-dipyrromethenes.
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Publisher |
AMER CHEMICAL SOC
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Date |
2012-06-26T08:59:45Z
2012-06-26T08:59:45Z 2011 |
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Type |
Article
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Identifier |
JOURNAL OF ORGANIC CHEMISTRY,76(20)8466-8471
0022-3263 http://dx.doi.org/10.1021/jo2010022 http://dspace.library.iitb.ac.in/jspui/handle/100/14244 |
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Language |
English
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