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Synthesis of Sterically Crowded Polyarylated Boron-Dipyrromethenes

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Field Value
 
Title Synthesis of Sterically Crowded Polyarylated Boron-Dipyrromethenes
 
Creator LAKSHMI, V
RAVIKANTH, M
 
Subject QUANTUM-CHEMICAL CALCULATIONS
FLUORESCENT BODIPY DYES
CRYSTAL-STRUCTURE
ELECTROCHEMISTRY
DERIVATIVES
SPECTROSCOPY
PHOTOPHYSICS
SEPARATION
COMPLEXES
CHEMISTRY
 
Description A rapid synthetic route for polyarylated boron-dipyrromethenes using hexabromo boron-dipyrromethene as the key synthon is described. The X-ray structure revealed that the polyarylated BODIPY adopts a propeller-like conformation. These compounds exhibit red-shifted absorption and fluorescence bands with decent quantum yields and reversible oxidation and reduction waves when compared to unsubstituted boron-dipyrromethenes.
 
Publisher AMER CHEMICAL SOC
 
Date 2012-06-26T08:59:45Z
2012-06-26T08:59:45Z
2011
 
Type Article
 
Identifier JOURNAL OF ORGANIC CHEMISTRY,76(20)8466-8471
0022-3263
http://dx.doi.org/10.1021/jo2010022
http://dspace.library.iitb.ac.in/jspui/handle/100/14244
 
Language English