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Lamellar Micelles as Templates for the Preparation of Silica Nanodisks

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Field Value
 
Title Lamellar Micelles as Templates for the Preparation of Silica Nanodisks
 
Creator BANERJEE, S
GHOSH, H
DATTA, A
 
Subject AOT REVERSE MICELLES
OIL-RICH REGIONS
SOL-GEL METHOD
MESOSTRUCTURED FLUIDS
WATER DYNAMICS
NANOTUBES
SIZE
NANOPARTICLES
MICROEMULSIONS
SPECTROSCOPY
 
Description We have reported earlier that silica nanodisks are formed by the reverse micelle sol-gel (RMSG) method, from ternary Aerosol OT (AOT)/n-heptane/water mixtures. These nanodisks are formed from the ternary mixtures with higher water contents and containing a significant concentration of FeCl(3). Such mixtures undergo a phase separation. The present work seeks to identify the origin of these nanodisks. They are found to be produced from the lower, water-rich layer and not from the upper, oil-rich layer or from the interfacial region. Further, upon increasing the water content by a factor of 10, the phase separation is achieved in the absence of the salt as well. In the next step, the naodisks are observed to form from concentrated aqueous AOT solutions, with no involvement of organic solvents. Polarized optical microscopy and infrared studies reveal the occurrence of lamellar AOT micelles in these media. These micelles act as the templates for the nanodisks. This phenomenon paves the way for the soft chemical preparation of nanodisks in the aqueous phase, without the need of using salt or organic solvents.
 
Publisher AMER CHEMICAL SOC
 
Date 2012-06-26T09:06:17Z
2012-06-26T09:06:17Z
2011
 
Type Article
 
Identifier JOURNAL OF PHYSICAL CHEMISTRY C,115(39)19023-19027
1932-7447
http://dx.doi.org/10.1021/jp205874k
http://dspace.library.iitb.ac.in/jspui/handle/100/14257
 
Language English