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Reactions of Di-o-tolyl Telluride and Selenide with Palladium Acetate: Isolation of a Novel Palladium Complex of a Tellurenic Acid Anhydride and Related Trinuclear and Tetranuclear Palladium Complexes

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Title Reactions of Di-o-tolyl Telluride and Selenide with Palladium Acetate: Isolation of a Novel Palladium Complex of a Tellurenic Acid Anhydride and Related Trinuclear and Tetranuclear Palladium Complexes
 
Creator CHAKRABORTY, T
SHARMA, S
SINGH, HB
BUTCHER, RJ
 
Subject SULFUR-CONTAINING PALLADACYCLES
X-RAY STRUCTURES
HECK REACTION
CATALYST PRECURSORS
COUPLING REACTIONS
METAL-COMPLEXES
CHEMISTRY
LIGANDS
PD(II)
CYCLOMETALATION
 
Description The reaction of di-o-tolyl telluride with palladium acetate provided a novel palladium complex of a tellurenic acid anhydride, (o-tolyl-Te)(2)OPdOAc(2), and a linear trinuclear complex, [Pd(o-tolyl){di-o-tolyl telluride}](2)Pd(mu-OAc)(2). The reaction of di-o-tolyl selenide with palladium acetate affoxded a tetranuclear complex of rare geometry, [Pd(OAc)(mu-Se-o-tolyl)](4).
 
Publisher AMER CHEMICAL SOC
 
Date 2012-06-26T09:10:18Z
2012-06-26T09:10:18Z
2011
 
Type Article
 
Identifier ORGANOMETALLICS,30(9)2525-2530
0276-7333
http://dx.doi.org/10.1021/om2000184
http://dspace.library.iitb.ac.in/jspui/handle/100/14265
 
Language English