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Chemoselectivity in the Cu-catalyzed O-arylation of phenols and aliphatic alcohols

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Field Value
 
Title Chemoselectivity in the Cu-catalyzed O-arylation of phenols and aliphatic alcohols
 
Creator MAITI, D
 
Subject COUPLING REACTIONS
N-ARYLATION
COPPER
CHEMISTRY
INVENTION
LIGANDS
HALIDES
ARYL
 
Description An orthogonal set of Cu-catalysts for the selective mono-arylation of alkyl aryl diols using aryl iodides is presented. Picolinic acid ligated copper catalyst provided phenol O-arylation only, while alkyl aryl ethers are generated by ligand-free copper catalyst in the presence of 2 equivalents NaOt-Bu.
 
Publisher ROYAL SOC CHEMISTRY
 
Date 2012-06-26T09:25:18Z
2012-06-26T09:25:18Z
2011
 
Type Article
 
Identifier CHEMICAL COMMUNICATIONS,47(29)8340-8342
1359-7345
http://dx.doi.org/10.1039/c1cc12694f
http://dspace.library.iitb.ac.in/jspui/handle/100/14281
 
Language English