Chemoselectivity in the Cu-catalyzed O-arylation of phenols and aliphatic alcohols
DSpace at IIT Bombay
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Title |
Chemoselectivity in the Cu-catalyzed O-arylation of phenols and aliphatic alcohols
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Creator |
MAITI, D
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Subject |
COUPLING REACTIONS
N-ARYLATION COPPER CHEMISTRY INVENTION LIGANDS HALIDES ARYL |
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Description |
An orthogonal set of Cu-catalysts for the selective mono-arylation of alkyl aryl diols using aryl iodides is presented. Picolinic acid ligated copper catalyst provided phenol O-arylation only, while alkyl aryl ethers are generated by ligand-free copper catalyst in the presence of 2 equivalents NaOt-Bu.
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Publisher |
ROYAL SOC CHEMISTRY
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Date |
2012-06-26T09:25:18Z
2012-06-26T09:25:18Z 2011 |
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Type |
Article
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Identifier |
CHEMICAL COMMUNICATIONS,47(29)8340-8342
1359-7345 http://dx.doi.org/10.1039/c1cc12694f http://dspace.library.iitb.ac.in/jspui/handle/100/14281 |
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Language |
English
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