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Synthesis of Biaryl Derivatives by Using Ruthenium-Mediated [2+2+2] Cyclotrimerization and Suzuki-Miyaura Cross-Coupling as Key Steps

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Title Synthesis of Biaryl Derivatives by Using Ruthenium-Mediated [2+2+2] Cyclotrimerization and Suzuki-Miyaura Cross-Coupling as Key Steps
 
Creator KOTHA, S
SEEMA, V
MOBIN, SM
 
Subject RING-CLOSING METATHESIS
DIELS-ALDER REACTION
TRANSITION-METAL-COMPLEXES
OLEFIN-METATHESIS
ENYNE METATHESIS
CLAISEN REARRANGEMENT
CATALYTIC METATHESIS
ALKYNE CYCLOTRIMERIZATION
CYCLOADDITION REACTIONS
STRUCTURAL ELUCIDATION
terphenyl
quinquephenyl
[2+2+2] cyclotrimerization
Suzuki-Miyaura cross-coupling
metathesis
 
Description Functionalized biaryl derivatives have been prepared by applying [2+2+2] cyclotrimerization with the aid of Grubbs' first-generation catalyst (G-I). The trimerized products were subjected to the Suzuki-Miyaura cross-coupling reaction sequence to generate highly functionalized biaryl derivatives.
 
Publisher GEORG THIEME VERLAG KG
 
Date 2012-06-26T09:38:21Z
2012-06-26T09:38:21Z
2011
 
Type Article
 
Identifier SYNTHESIS-STUTTGART,(10)1581-1586
0039-7881
http://dx.doi.org/10.1055/s-0030-1260009
http://dspace.library.iitb.ac.in/jspui/handle/100/14307
 
Language English