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Total Synthesis and Stereochemical Assignment of (-)-Zenkequinone B

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Title Total Synthesis and Stereochemical Assignment of (-)-Zenkequinone B
 
Creator VANGA, DG
KALIAPPAN, KP
 
Subject Sharpless epoxidation
enyne metathesis
Diels-Alder reaction
total synthesis
ENANTIOSELECTIVE TOTAL-SYNTHESIS
ANTIBIOTICS (+)-RUBIGINONE B-2
DIELS-ALDER REACTION
C-ARYL GLYCOSIDES
ANGUCYCLINE ANTIBIOTICS
URDAMYCINONE-B
RACEMIC VINYLCYCLOHEXENES
ASYMMETRIC-SYNTHESIS
(+)-OCHROMYCINONE
(-)-TETRANGOMYCIN
 
Description The first enantioselective total synthesis and a concise racemic synthesis of zenkequinone B are reported here by utilizing a sequential enyne metathesis, Diels-Alder and aromatization reactions.
 
Publisher GEORG THIEME VERLAG KG
 
Date 2014-10-14T13:12:38Z
2014-10-14T13:12:38Z
2012
 
Type Article
 
Identifier SYNLETT, (20)2931-2934
http://dx.doi.org/10.1055/s-0032-1317519
http://dspace.library.iitb.ac.in/jspui/handle/100/14490
 
Language en