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Highly selective liquid-liquid extraction of cadmium(II) with hexaacetato calix(6)arene

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Title Highly selective liquid-liquid extraction of cadmium(II) with hexaacetato calix(6)arene
 
Creator THAKARE, YS
KHOPKAR, SM
MALKHEDE, DD
 
Subject Acetyl derivative
Cadmium(II)
Calix(6)arene
Separation
Solvent extraction
SOLID-PHASE EXTRACTION
ATOMIC-ABSORPTION-SPECTROMETRY
PHOSPHORIC-ACID SOLUTIONS
SOLVENT-EXTRACTION
MEDIA
MIXTURES
CHLORIDE
AMINES
COPPER
ZINC
 
Description In this study, cadmium(II) has been extracted with 10 mL of 0.0001 M acetyl derivative of calix(6)arene at pH 8.0 by equilibrating for 5 mm Cadmium(II) is stripped quantitatively with 0.5 N hydrochloric acid and determined photometrically by complexation with 4-(2-pyridylazo)resorcinol at 495 nm. The method affords the binary separation of cadmium from associate elements and is further extended to analyse the synthetic mixtures. The nature of the extracted species is determined from the log-log plots. The result shows the formation of an ion pair complex [Cd(HR)(2)](org) in the organic phase. The temperature dependence of the extraction equilibrium is examined by the temperature variation method. The value of square H-0 = +160485.48 J mole(-1) indicates that the extraction reaction is endothermic. The metal loading capacity of the reagent is found to be 150 ppm. The proposed method is applicable to the analysis of real samples and the results obtained are found to be reproducible and accurate.
 
Publisher NATL INST SCIENCE COMMUNICATION-NISCAIR
 
Date 2014-10-14T17:07:48Z
2014-10-14T17:07:48Z
2012
 
Type Article
 
Identifier INDIAN JOURNAL OF CHEMICAL TECHNOLOGY, 19(4)231-238
http://dspace.library.iitb.ac.in/jspui/handle/100/14528
 
Language en