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Intramolecular C-C coupling of 2,6-disubstituted-1-bromoaryls for dihydrophenanthridines

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Title Intramolecular C-C coupling of 2,6-disubstituted-1-bromoaryls for dihydrophenanthridines
 
Creator SINGH, VP
SINGH, P
SINGH, HB
BUTCHER, RJ
 
Subject Intramolecular C-C coupling
Phenanthridine
Dihydrophenanthridine
TOLUAMIDE-BENZONITRILE CYCLOADDITION
CONDENSED POLYNUCLEAR COMPOUNDS
SODIUM BOROHYDRIDE
DERIVATIVES
REDUCTION
PHENANTHRIDINES
CYCLIZATION
ALKALOIDS
ROUTES
BASES
 
Description The reaction of 2,6-disubstituted-1-bromoaryl imines with sodium borohydride under reflux condition leads to an intramolecular cyclization through C-Br and C-H coupling without any transition-metal catalyst, furnishing 5,6-dihydrophenanthridine and phenanthridine derivatives. (C) 2012 Elsevier Ltd. All rights reserved.
 
Publisher PERGAMON-ELSEVIER SCIENCE LTD
 
Date 2014-10-14T17:48:16Z
2014-10-14T17:48:16Z
2012
 
Type Article
 
Identifier TETRAHEDRON LETTERS, 53(34)4591-4594
http://dx.doi.org/10.1016/j.tetlet.2012.06.087
http://dspace.library.iitb.ac.in/jspui/handle/100/14607
 
Language en