Intramolecular C-C coupling of 2,6-disubstituted-1-bromoaryls for dihydrophenanthridines
DSpace at IIT Bombay
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Title |
Intramolecular C-C coupling of 2,6-disubstituted-1-bromoaryls for dihydrophenanthridines
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Creator |
SINGH, VP
SINGH, P SINGH, HB BUTCHER, RJ |
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Subject |
Intramolecular C-C coupling
Phenanthridine Dihydrophenanthridine TOLUAMIDE-BENZONITRILE CYCLOADDITION CONDENSED POLYNUCLEAR COMPOUNDS SODIUM BOROHYDRIDE DERIVATIVES REDUCTION PHENANTHRIDINES CYCLIZATION ALKALOIDS ROUTES BASES |
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Description |
The reaction of 2,6-disubstituted-1-bromoaryl imines with sodium borohydride under reflux condition leads to an intramolecular cyclization through C-Br and C-H coupling without any transition-metal catalyst, furnishing 5,6-dihydrophenanthridine and phenanthridine derivatives. (C) 2012 Elsevier Ltd. All rights reserved.
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Publisher |
PERGAMON-ELSEVIER SCIENCE LTD
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Date |
2014-10-14T17:48:16Z
2014-10-14T17:48:16Z 2012 |
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Type |
Article
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Identifier |
TETRAHEDRON LETTERS, 53(34)4591-4594
http://dx.doi.org/10.1016/j.tetlet.2012.06.087 http://dspace.library.iitb.ac.in/jspui/handle/100/14607 |
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Language |
en
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