A Concise Total Synthesis of (+)-Cladospolide D
DSpace at IIT Bombay
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Title |
A Concise Total Synthesis of (+)-Cladospolide D
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Creator |
SI, D
KALIAPPAN, KP |
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Subject |
olefin cross-metathesis
Julia-Kocienski olefination Yamaguchi lactonization cladospolides total synthesis RING-CLOSING METATHESIS FORMAL TOTAL-SYNTHESIS ISO-CLADOSPOLIDE-B MEDIUM-SIZED RINGS OLEFIN METATHESIS ORGANIC-SYNTHESIS EFFICIENT SYNTHESIS NATURAL-PRODUCTS MACROLIDE STRATEGY |
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Description |
A short and convergent total synthesis of (+)-cladospolide D is delineated, which involves olefin cross metathesis and furan oxidation to access the gamma-oxo-alpha,beta-unsaturated acid and Yamaguchi lactonization to construct the 12-membered ring as key steps.
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Publisher |
GEORG THIEME VERLAG KG
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Date |
2014-10-15T08:16:33Z
2014-10-15T08:16:33Z 2012 |
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Type |
Article
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Identifier |
SYNLETT, (19)2822-2826
http://dx.doi.org/10.1055/s-0032-1317520 http://dspace.library.iitb.ac.in/jspui/handle/100/14660 |
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Language |
en
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